Unusually high porosity in polymeric cluster cyanides:: the synthesis and crystal structure of(H3O)2Zn3 [Re6Se8(CN)6]2•20H2O

被引：0
|
作者：
Naumov, NG [1 ]
Virovets, AV [1 ]
Fedorov, VE [1 ]
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 02期
关键词：
crystal structures; cluster compounds; rhenium complexes; cyanide complexes; porosity; polymers;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Mixing of aqueous solutions of the cluster anion [Re(6)Se(8)(CN)(6)](4-) and Zn(2+) in the presence of acetic acid (pH 3) leads to precipitation of (H(3)O)(2)Zn(3)[Re(6)Se(8)(CN)(6)](2). 20H(2)O having a three dimensional framework of {Zn(3)[Re(6)Se(8)(CN)(6)](2)}(2-) formed by Re-C=N-Zn covalent interactions. This framework occupies only 41.9% of the unit cell volume. The rest of the space is tilled by disordered water molecules and hydroxonium cations. (C) 2000 Published by Elsevier Science S.A. All rights reserved.
引用
收藏
页码：71 / 72
页数：2
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