Unusually high porosity in polymeric cluster cyanides:: the synthesis and crystal structure of(H3O)2Zn3 [Re6Se8(CN)6]2•20H2O

被引：0
|
作者：
Naumov, NG [1 ]
Virovets, AV [1 ]
Fedorov, VE [1 ]
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 02期
关键词：
crystal structures; cluster compounds; rhenium complexes; cyanide complexes; porosity; polymers;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Mixing of aqueous solutions of the cluster anion [Re(6)Se(8)(CN)(6)](4-) and Zn(2+) in the presence of acetic acid (pH 3) leads to precipitation of (H(3)O)(2)Zn(3)[Re(6)Se(8)(CN)(6)](2). 20H(2)O having a three dimensional framework of {Zn(3)[Re(6)Se(8)(CN)(6)](2)}(2-) formed by Re-C=N-Zn covalent interactions. This framework occupies only 41.9% of the unit cell volume. The rest of the space is tilled by disordered water molecules and hydroxonium cations. (C) 2000 Published by Elsevier Science S.A. All rights reserved.
引用
收藏
页码：71 / 72
页数：2
相关论文
共 50 条
  • [21] Synthesis, characterisation and structural studies of [Zn(phen)3][Fe(CN)5(NO)]•2H2O•0.25MeOH and [(bipy)2(H2O)Zn(μ-NC)Fe(CN)4(NO)]•0.5H2O
    Datta, A
    Mitra, S
    Rosair, G
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2003, 58 (09): : 916 - 921
  • [22] Synthesis and characterization of cyano-bridged polynuclear [Cu(dmpn)2]3[Co(CN)6]2•12H2O and trinuclear [Cu(dmpn)2]2[Co(CN)6]•ClO4•3H2O complexes
    Mondal, N
    Dey, DK
    Mitra, S
    Gramlich, V
    POLYHEDRON, 2001, 20 (7-8) : 607 - 613
  • [23] Isostructural series of [{Al(H2O)6}{Ln(pda)3}]•10H2O: Synthesis, structure and photoluminescence
    Kumar, Dinesh
    Tewari, Shailabh
    Adnan, Mohammad
    Ahmad, Shahab
    Prakash, G. Vijaya
    Ramanan, Arunachalam
    INORGANICA CHIMICA ACTA, 2019, 487 : 81 - 91
  • [24] Two new polyoxovanadate-supported transition metal complexes:: [Zn(en)2][Zn(en)2(H2O)2][{Zn(en)(enMe)}As6V15O42(H2O)•4H2O and [Zn2(enMe)2(en)3][{Zn(enMe)2}As6V15O42(H2O)•4H2O
    Zheng, ST
    Chen, YM
    Zhang, M
    Yang, GY
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (01): : 155 - 159
  • [25] Crystal structures of two solvates of molybdenum octahedral clusters: (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]•2CH3CN and (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]•2CH2Cl2
    Sokolov, M. N.
    Mikhailov, M. A.
    Abramov, P. A.
    Fedin, V. P.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 53 (01) : 197 - 201
  • [26] Hydrothermal synthesis and crystal structure of a new molybdenum(VI) arsenate(III), CoIII(en)3H3O[(CoIIO6)Mo6VIO18(As3IIIO3)2]•2H2O
    He, QL
    Wang, EB
    INORGANICA CHIMICA ACTA, 1999, 295 (02) : 244 - 247
  • [27] Structures and thermal decomposition of enH2(H3O)[AIF6] and enH2[AlF5(H2O)]
    Bentrup, U
    Ahmadi, A
    Kang, HC
    Massa, W
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (09): : 1465 - 1470
  • [28] Crystal structures of two solvates of molybdenum octahedral clusters: (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH3CN and (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH2Cl2
    M. N. Sokolov
    M. A. Mikhailov
    P. A. Abramov
    V. P. Fedin
    Journal of Structural Chemistry, 2012, 53 : 197 - 201
  • [29] Synthesis and structure analysis of three new lanthanide complexes, [Ce(NO3)6 ]•[(H-&(NO3)3], [Pr(NO3)6]•[(H-&(NO3)3] and [Sm(NO3)3•(&(H2O)2]•[(H-&(NO3)•H2O]
    Giri, Lopamudra
    Pedireddi, V. R.
    INORGANICA CHIMICA ACTA, 2018, 477 : 160 - 164
  • [30] PREPARATION AND CRYSTAL-STRUCTURE OF RB2SN3S7.2H2O AND RB4SN2SE6
    SHELDRICK, WS
    SCHAAF, B
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (06): : 1041 - 1045
12345