Unusually high porosity in polymeric cluster cyanides:: the synthesis and crystal structure of(H3O)2Zn3 [Re6Se8(CN)6]2•20H2O

被引：0
|
作者：
Naumov, NG [1 ]
Virovets, AV [1 ]
Fedorov, VE [1 ]
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 02期
关键词：
crystal structures; cluster compounds; rhenium complexes; cyanide complexes; porosity; polymers;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Mixing of aqueous solutions of the cluster anion [Re(6)Se(8)(CN)(6)](4-) and Zn(2+) in the presence of acetic acid (pH 3) leads to precipitation of (H(3)O)(2)Zn(3)[Re(6)Se(8)(CN)(6)](2). 20H(2)O having a three dimensional framework of {Zn(3)[Re(6)Se(8)(CN)(6)](2)}(2-) formed by Re-C=N-Zn covalent interactions. This framework occupies only 41.9% of the unit cell volume. The rest of the space is tilled by disordered water molecules and hydroxonium cations. (C) 2000 Published by Elsevier Science S.A. All rights reserved.
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页码：71 / 72
页数：2
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