Synthesis and characterization of one novel second-order nonlinear optical chromophore based on new benzoxazin donor

被引：9

作者：

Wang, Haoran ^{[1
,2
]}

Zhang, Maolin ^{[1
,2
]}

Yang, Yuhui ^{[1
,2
]}

Liu, Fenggang ^{[1
,2
]}

Hu, Chaolei ^{[1
,2
]}

Xiao, Hongyan ^{[1
]}

Qiu, Ling ^{[1
]}

Liu, Xinhou ^{[1
]}

Liu, Jialei ^{[1
]}

Zhen, Zhen ^{[1
]}

机构：

[1] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100043, Peoples R China

来源：

MATERIALS LETTERS | 2016年 / 164卷

基金：

中国国家自然科学基金;

关键词：

Electronic materials; Thin films; Organic; NLO; Chromophore; EO coefficient; DYES;

D O I：

10.1016/j.matlet.2015.11.085

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

One novel second order nonlinear optical chromophore based on benzoxazin donor and tricyanovinyldihydrofuran acceptor linked together via thiophene bridge has been synthesized and characterized. According to cyclic voltammetry measurement, chromophore Z showed low energy gap. In addition, chromophore Z displayed good thermal stability with the onset decomposition temperature over 221 degrees C. The electro-optic coefficient of a poled film containing 25 wt% of chromophore Z doped in polymethylmethacrylate afforded a value of 64 pm/V at 1310 nm. The result showed that chromophore Z, which had good thermal stability and high r(33) values after poling in films, was a promising candidate for practical use. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：644 / 646

页数：3

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