Synthesis, crystal structure, and photoluminescence of a zinc metalloporphyrin

被引：4
|
作者：
Chen, Wen-Tong [1 ,2 ]
Yi, Xiu-Guang [1 ]
Luo, Zhi-Gang [1 ]
Fu, Hong-Ru [2 ]
Liu, Juan [2 ]
机构：
[1] Jinggangshan Univ, Jiangxi Prov Key Lab Coordinat Chem, Sch Chem & Chem Engn, Inst Appl Chem, Jian 343009, Jiangxi, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2014年 / 88卷 / 07期
关键词：
metalloporphyrin; photoluminescence; solvothermal; zinc; COMPLEX;
D O I：
10.1134/S0036024414070309
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A zinc metalloporphyrin, ZnTCPP(acetone) (1) (TCPP = meso-tetra(4-carboxyphenyl)porphyrin), has been prepared via a solvothermal reaction and structurally characterized by single-crystal X-ray diffraction. Compound 1 features an isolated structure with a planar macrocycle and an embedded zinc ion binded to four pyrrole nitrogen atoms and one acetone oxygen atom. Photoluminescent investigation reveals that compound 1 displays an intensive emission in the red region.
引用
收藏
页码：1228 / 1231
页数：4
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