Uranium Tetrakis-Aryloxide Derivatives Supported by Tetraazacyclododecane: Synthesis of Air-Stable, Coordinatively-Unsaturated U(IV) and U(V) Complexes

被引：19

作者：

Hummer, Julian ^{[1
]}

Heinemann, Frank W. ^{[1
]}

Meyer, Karsten ^{[1
]}

机构：

[1] Friedrich Alexander Univ Erlangen Nurnberg, Dept Chem & Pharm, Inorgan Chem, Egerlandstr 1, D-91058 Erlangen, Germany

来源：

INORGANIC CHEMISTRY | 2017年 / 56卷 / 06期

关键词：

ACTIVATION; REACTIVITY; CHEMISTRY; TRIAZACYCLONONANE; MOLECULES; LIGANDS; VALENT; FORM; OXO;

D O I：

10.1021/acs.inorgchem.6b02123

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We present the synthesis, characterization, and one -electron oxidation of two uranium(IV) complexes, coordinated to the cyclen-anchored tetrakis(aryloxide) ligands tetrakishy hydroxybenzyl- 1, 4,7, 1 0 tetraazacyclododecane, ((ArOH)-Ar-R,R)(4)cyclen; R = Bu-t, Me. The new uranium(IV) and (V) complexes exhibit an eight -coordinate, tetragonal ligand environment, effecting exceptional stability of the coordinatively unsaturated uranium compounds. Cyclic voltammetry studies reveal redox events ranging from- tri- to hexavalent species, covering an electrochemical window of similar to 4 V.

引用

页码：3201 / 3206

页数：6

共 7 条

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