A very large Rh-Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction

被引：70
作者：
Coppens, P [1 ]
Gerlits, O
Vorontsov, II
Kovalevsky, AY
Chen, YS
Graber, T
Gembicky, M
Novozhilova, IV
机构：
[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA
[2] Univ Toledo, Toledo, OH 43606 USA
[3] Univ Chicago, Chicago, IL 60637 USA
来源：
CHEMICAL COMMUNICATIONS | 2004年 / 19期
关键词：
D O I：
10.1039/b409463h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A very large Rh - Rh contraction of similar to0.85 Angstrom occurs on excitation of the [Rh-2(1,8-diisocyano-p-menthane)(4)](2+) ion to its triplet state.
引用
收藏
页码：2144 / 2145
页数：2
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