Effect of SO3 content and fineness on the rate of delayed ettringite formation in heat cured Portland cement mortars

This paper presents the findings of a long-term study on the expansion rate and microstructure of heat cured cement mortars. For this purpose, cements with different fineness and SO3 contents were produced by using the same clinker. Different mortar specimens were prepared and subjected to heat curing. Length changes of specimens were measured within a period of 540 days. The microstructures of young (2 day after heat curing) and old (1.5 years after heat curing) specimens were also investigated by SEM and EDS analysis. The expansion rates and microstructures observed were compared with the control specimens. Results showed that, at the initial stages of testing (2-3 months), expansion rates of heat cured mortars prepared with finer cements were less than those prepared with coarser cements. However, in the long term, the rate of expansion of mortars prepared with finer cements exceeded the coarser ones' expansion values. This result may be attributed to the different hydration characteristics and pore structure of heat cured mortars including cements of different fineness. (c) 2006 Elsevier Ltd. All rights reserved.