Emergent magnetic properties of biphase iron oxide nanorods

被引:5
作者
Attanayake, S. B. [1 ]
Chanda, A. [1 ]
Das, R. [2 ]
Phan, M. H. [1 ]
Srikanth, H. [1 ]
机构
[1] Univ S Florida, Dept Phys, Tampa, FL 33620 USA
[2] Phenikaa Univ, Fac Mat Sci & Engn, Hanoi 12116, Vietnam
关键词
FERRIMAGNETIC/FERROELASTIC DOMAIN INTERACTIONS; VERWEY TRANSITION; LOW-TEMPERATURE; HYPERTHERMIA; FE3O4; COERCIVITY;
D O I
10.1063/9.0000256
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We report on the magnetic properties of biphase iron oxide nanorods (NRs) consisting of ferrimagnetic Fe3O4 and antiferromagnetic alpha-Fe2O3 phases. Annealing as-prepared NRs at 250 degrees C for 5h, significantly improved the crystallinity of the Fe3O4 phase and enhanced the volume fraction of the alpha-Fe2O3 phase. Magnetometry data consistently reveal these two magnetically distinct phases, which are not in proximity to each other but separated by a region of disordered spins giving rise to enhanced magnetization at low temperatures when the sample was cooled down from 300 K in the presence of a 1T field to 10 K. This phenomenon which is also known as the pinning effect is much more pronounced in the annealed sample, resulting from the increased volume fraction of the alpha-Fe2O3 phase which could strengthen the interfacial spin frustration between these two phases and enhance the density of disordered spins at the interface. (C) 2022 Author(s).
引用
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页数:5
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共 40 条
  • [21] Learning from Nature to Improve the Heat Generation of Iron-Oxide Nanoparticles for Magnetic Hyperthermia Applications
    Martinez-Boubeta, Carlos
    Simeonidis, Konstantinos
    Makridis, Antonios
    Angelakeris, Makis
    Iglesias, Oscar
    Guardia, Pablo
    Cabot, Andreu
    Yedra, Lluis
    Estrade, Sonia
    Peiro, Francesca
    Saghi, Zineb
    Midgley, Paul A.
    Conde-Leboran, Ivan
    Serantes, David
    Baldomir, Daniel
    [J]. SCIENTIFIC REPORTS, 2013, 3
  • [22] Domain structures in single crystal magnetite below the Verwey transition as observed with a low-temperature magnetic force microscope
    Moloni, K
    Moskowitz, BM
    Dahlberg, ED
    [J]. GEOPHYSICAL RESEARCH LETTERS, 1996, 23 (20) : 2851 - 2854
  • [23] Origin of reduced magnetization and domain formation in small magnetite nanoparticles
    Nedelkoski, Zlatko
    Kepaptsoglou, Demie
    Lari, Leonardo
    Wen, Tianlong
    Booth, Ryan A.
    Oberdick, Samuel D.
    Galindo, Pedro L.
    Ramasse, Quentin M.
    Evans, Richard F. L.
    Majetich, Sara
    Lazarov, Vlado K.
    [J]. SCIENTIFIC REPORTS, 2017, 7
  • [24] Enhanced Magnetic Hyperthermia in Iron Oxide Nano-Octopods: Size and Anisotropy Effects
    Nemati, Z.
    Alonso, J.
    Martinez, L. M.
    Khurshid, H.
    Garaio, E.
    Garcia, J. A.
    Phan, M. H.
    Srikanth, H.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (15) : 8370 - 8379
  • [25] Exchange bias in Fe/Fe3O4 core-shell magnetic nanoparticles mediated by frozen interfacial spins
    Ong, Quy Khac
    Wei, Alexander
    Lin, Xiao-Min
    [J]. PHYSICAL REVIEW B, 2009, 80 (13):
  • [26] Changes in remanence, coercivity and domain state at low temperature in magnetite
    Özdemir, Ö
    Dunlop, DJ
    Moskowitz, BM
    [J]. EARTH AND PLANETARY SCIENCE LETTERS, 2002, 194 (3-4) : 343 - 358
  • [27] Effect of electric/magnetic field on pinned/biased moments at the interfaces of magnetic superlattices
    Padhan, P
    Prellier, W
    [J]. JOURNAL OF APPLIED PHYSICS, 2005, 98 (08)
  • [28] Entropy change linked to the magnetic field induced Morin transition in Hematite nanoparticles
    Pastor, J. M.
    Perez-Landazabal, J. I.
    Gomez-Polo, C.
    Recarte, V.
    Larumbe, S.
    Santamarta, R.
    Fernandes Silva, M.
    Gomez Pineda, E. A.
    Winkler Hechenleitner, A. A.
    Lima, M. K.
    [J]. APPLIED PHYSICS LETTERS, 2012, 100 (06)
  • [29] Morin transition in Hematite nanoparticles analyzed by neutron diffraction
    Perez-Landazabal, J. I.
    Gomez-Polo, C.
    Recarte, V.
    Larumbe, S.
    Sanchez-Alarcos, V.
    Fernandes Silva, M.
    Gomez Pineda, E. A.
    Winkler Hechenleitner, A. A.
    Lima, M. K.
    Rodriguez-Velamazan, J. A.
    [J]. 7TH MEETING OF THE SPANISH NEUTRON SCATTERING ASSOCIATION (SETN), 2015, 663
  • [30] MORIN TRANSITION IN ALPHA-FE2O3 MICROCRYSTALS
    SCHROEER, D
    NININGER, RC
    [J]. PHYSICAL REVIEW LETTERS, 1967, 19 (11) : 632 - &