Solar-driven CO2 conversion promoted by MOF - on - MOF homophase junction

被引：29

作者：

Yu, Yan ^{[2
]}

Li, Shuqi ^{[1
]}

Huang, Lu ^{[1
]}

Yu, Jie ^{[3
]}

Zhang, Haiyan ^{[1
]}

Song, Shuang ^{[1
]}

Zeng, Tao ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Environm, Key Lab Microbial Technol Ind Pollut Control Zhej, Hangzhou 310032, Peoples R China

[2] Ningbo Univ, Coll Sci & Technol, Ningbo 315212, Peoples R China

[3] China Jiliang Univ, Coll Qual & Safety Engn, Dept Environm Engn, Hangzhou 310018, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2021年 / 150卷

基金：

中国国家自然科学基金;

关键词：

MOF-on-MOF; Phase junction; Photocatalysts; CO2; conversion; METAL-ORGANIC FRAMEWORK; FORMIC-ACID; PHOTOCATALYST; REDUCTION; NANOCOMPOSITES;

D O I：

10.1016/j.catcom.2020.106270

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We herein reported the first case of successfully synthesizing homologous Ti(IV) - based metal-organic frameworks (MOFs) junction, comprising NH2-MIL-125 core and NTU-9 layer, via a MOF-on-MOF strategy. Benefiting from the core-shell structural advantages and the homophase type II junction effect, the obtained NH2-MIL-125@NTU-9 hybrids exhibit accelerated reaction kinetics and enhanced electron transfer behaviour in the solar-driven CO2 reduction. The quantum efficiency of formate production at 430 nm (0.67%) and product selectivity (94.47%) over NH2-MIL-125@NTU-9 far surpass those of the pure NH2-MIL-125 (0.13%, 88.56%) and NTU-9 (0.16%, 89.26%), which is among the highest performances of MOFs reported previously.

引用

页数：6

共 26 条

[1] Phase junction CdS: High efficient and stable photocatalyst for hydrogen generation [J].

Ai, Zizheng ;

Zhao, Gang ;

Zhong, Yueyao ;

Shao, Yongliang ;

Huang, Baibiao ;

Wu, Yongzhong ;

Hao, Xiaopeng .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 221 :179-186

[2] In Situ Grown Monolayer N-Doped Graphene on CdS Hollow Spheres with Seamless Contact for Photocatalytic CO2 Reduction [J].

Bie, Chuanbiao ;

Zhu, Bicheng ;

Xu, Feiyan ;

Zhang, Liuyang ;

Yu, Jiaguo .

ADVANCED MATERIALS, 2019, 31 (42)

[3] Maximizing the Photocatalytic Activity of Metal-Organic Frameworks with Aminated-Functionalized Linkers: Substoichiometric Effects in MIL-125-NH2 [J].

Chambers, Matthew B. ;

Wang, Xia ;

Ellezam, Laura ;

Ersen, Ovidiu ;

Fontecave, Marc ;

Sanchez, Clement ;

Rozes, Laurence ;

Mellot-Draznieks, Caroline .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (24) :8222-8228

[4] Boosting the photocatalytic activity of CdLa2S4 for hydrogen production using Ti3C2 MXene as a co-catalyst [J].

Cheng, Lin ;

Chen, Qian ;

Li, Juan ;

Liu, Hong .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 267

[5] CO2 capture and photocatalytic reduction using bifunctional TiO2/MOF nanocomposites under UV-vis irradiation [J].

Crake, Angus ;

Christoforidis, Konstantinos C. ;

Kafizas, Andreas ;

Zafeiratos, Spyridon ;

Petit, Camille .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2017, 210 :131-140

[6] Synergistic Doping and Intercalation: Realizing Deep Phase Modulation on MoS2 Arrays for High-Efficiency Hydrogen Evolution Reaction [J].

Deng, Shengjue ;

Luo, Mi ;

Ai, Changzhi ;

Zhang, Yan ;

Liu, Bo ;

Huang, Lei ;

Jiang, Zheng ;

Zhang, Qinghua ;

Gu, Lin ;

Lin, Shiwei ;

Wang, Xiuli ;

Yu, Lei ;

Wen, Jianguo ;

Wang, Jiaao ;

Pan, Guoxiang ;

Xia, Xinhui ;

Tu, Jiangping .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (45) :16289-16296

[7] A direct Z-scheme g-C3N4/SnS2 photocatalyst with superior visible-light CO2 reduction performance [J].

Di, Tingmin ;

Zhu, Bicheng ;

Cheng, Bei ;

Yu, Jiaguo ;

Xu, Jingsan .

JOURNAL OF CATALYSIS, 2017, 352 :532-541

[8] Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes [J].

Feaster, Jeremy T. ;

Shi, Chuan ;

Cave, Etosha R. ;

Hatsukade, Tom T. ;

Abram, David N. ;

Kuhl, Kendra P. ;

Hahn, Christopher ;

Norskov, Jens K. ;

Jaramillo, Thomas F. .

ACS CATALYSIS, 2017, 7 (07) :4822-4827

[9] A p-type Ti( IV)-based metal-organic framework with visible-light photo-response [J].

Gao, Junkuo ;

Miao, Jianwei ;

Li, Pei-Zhou ;

Teng, Wen Yuan ;

Yang, Ling ;

Zhao, Yanli ;

Liu, Bin ;

Zhang, Qichun .

CHEMICAL COMMUNICATIONS, 2014, 50 (29) :3786-3788

[10] Preparation of nanocomposites of polyaniline and inorganic semiconductors [J].

Godovsky, DY ;

Varfolomeev, AE ;

Zaretsky, DF ;

Chandrakanthi, RLN ;

Kündig, A ;

Weder, C ;

Caseri, W .

JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (10) :2465-2469

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