Optical properties of two-dimensional semi-conductive MXene Sc2COx produced by sputtering

被引:25
作者
Chen, Qiran [1 ]
Zhang, Daohua [1 ]
Pan, Jisheng [2 ]
Fan, Weijun [1 ]
机构
[1] Nanyang Technol Univ, Sch Elect & Elect Engn, Singapore 639197, Singapore
[2] Agcy Sci Technol & Res, Inst Mat Res & Engn IMRE, Singapore, Singapore
来源
OPTIK | 2020年 / 219卷
关键词
MXene; Semiconductor; Sputtering; Scandium; ELECTRONIC-STRUCTURE; TI3C2X2; X; ANODE; OH; NANOCARBIDES; CARBIDES; SC2O3;
D O I
10.1016/j.ijleo.2020.165046
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Semi-conductive MXene Sc2COx is synthesized by using magnetron sputtering. X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) is performed to determine the composition of sample. The bandgap of Sc2COx sample is determined by ultraviolet-visible (UV-VIS) range absorption and photoluminescence (PL) spectrum. The Tauc plot indicates that Sc2COx is a direct bandgap material. The high sensitivity of scandium to oxygen makes the sample contain both scandium carbide and scandium oxide. Thermal annealing introduces more oxidation into the sample. Structure of MXene will be broken when the annealing temperature is higher than 600 degrees C.
引用
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页数:7
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共 36 条
[1]   Synthesis of cobalt oxide (Co3O4) thin films by electrostatic spray pyrolysis technique (ESP) [J].
Abbas, Tariq Abdul-Hameed ;
Slewa, Lary Hana ;
Khizir, Hersh Ahmed ;
Kakil, Shaida Anwer .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (02) :1951-1957
[2]   Electronic structure of silicon interfaces with amorphous and epitaxial insulating oxides:: Sc2O3, Lu2O3, LaLuO3 [J].
Afanas'ev, V. V. ;
Shamuilia, S. ;
Badylevich, M. ;
Stesmans, A. ;
Edge, L. F. ;
Tian, W. ;
Schlom, D. G. ;
Lopes, J. M. J. ;
Roeckerath, M. ;
Schubert, J. .
MICROELECTRONIC ENGINEERING, 2007, 84 (9-10) :2278-2281
[3]   The MN+1AXN phases:: A new class of solids;: Thermodynamically stable nanolaminates [J].
Barsoum, MW .
PROGRESS IN SOLID STATE CHEMISTRY, 2000, 28 (1-4) :201-281
[4]   Two-dimensional titanium carbonitrides and their hydroxylated derivatives: Structural, electronic propertis and stability of MXenes Ti3C2-xNx(OH)2 from DFTB calculations [J].
Enyashin, A. N. ;
Ivanovskii, A. L. .
JOURNAL OF SOLID STATE CHEMISTRY, 2013, 207 :42-48
[5]   Synthesis and characterization of two-dimensional Nb4C3 (MXene) [J].
Ghidiu, M. ;
Naguib, M. ;
Shi, C. ;
Mashtalir, O. ;
Pan, L. M. ;
Zhang, B. ;
Yang, J. ;
Gogotsi, Y. ;
Billinge, S. J. L. ;
Barsoum, M. W. .
CHEMICAL COMMUNICATIONS, 2014, 50 (67) :9517-9520
[6]   Conductive two-dimensional titanium carbide 'clay' with high volumetric capacitance [J].
Ghidiu, Michael ;
Lukatskaya, Maria R. ;
Zhao, Meng-Qiang ;
Gogotsi, Yury ;
Barsoum, Michel W. .
NATURE, 2014, 516 (7529) :78-U171
[7]   Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films [J].
Halim, Joseph ;
Lukatskaya, Maria R. ;
Cook, Kevin M. ;
Lu, Jun ;
Smith, Cole R. ;
Naslund, Lars-Ake ;
May, Steven J. ;
Hultman, Lars ;
Gogotsi, Yury ;
Eklund, Per ;
Barsoum, Michel W. .
CHEMISTRY OF MATERIALS, 2014, 26 (07) :2374-2381
[8]   Vibrational properties of Ti3C2 and Ti3C2T2 (T = O, F, OH) monosheets by first-principles calculations: a comparative study [J].
Hu, Tao ;
Wang, Jiemin ;
Zhang, Hui ;
Li, Zhaojin ;
Hu, Minmin ;
Wang, Xiaohui .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (15) :9997-10003
[9]   Graphene-like transition-metal nanocarbides and nanonitrides [J].
Ivanovskii, A. L. ;
Enyashin, A. N. .
RUSSIAN CHEMICAL REVIEWS, 2013, 82 (08) :735-746
[10]   Nearly free electron states in MXenes [J].
Khazaei, Mohammad ;
Ranjbar, Ahmad ;
Ghorbani-Asl, Mahdi ;
Arai, Masao ;
Sasaki, Taizo ;
Liang, Yunye ;
Yunoki, Seiji .
PHYSICAL REVIEW B, 2016, 93 (20)