Acylated anthocyanins from the blue-violet flowers of Anemone coronaria

被引:32
作者
Saito, N
Toki, K
Moriyama, H
Shigihara, A
Honda, T [1 ]
机构
[1] Hoshi Univ, Fac Pharmaceut Sci, Shinagawa Ku, Tokyo, Japan
[2] Meiji Gakuin Univ, Chem Lab, Yokohama, Kanagawa, Japan
[3] Minami Kyusyu Univ, Lab Floriculture, Miyazaki, Japan
关键词
Anemone coronaria; Ranunculaceae; blue-violet flower color; acylated anthocyanins; delphinidin and cyanidin; 3-glucosylgalactoside-7-glucoside-3 '-glucuronides; caffeic acid; malonic acid; tartaric acid; anthocyanin and tartaric acid disubstituted malonate;
D O I
10.1016/S0031-9422(02)00097-3
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Five polyacylated anthocyanins were isolated from blue-violet flowers of Anemone coronaria 'St. Brigid'. They were identified as delphinidin 3-O-[2-O-(2-O-(trans-caffeoyl)-beta-D-glucopyranosyl)-6-O-(malonyl)-beta-D-galactopyranoside]-7-O-[6-O-(trans-caffeoyl)-beta-D-glucopyranoside]-3'-O-[beta-D-glucuronopyranoside], and its demalonylated form, delphinidin 3-O-[2-O-(2-O-(trans-caffeoyl)-beta-D-glucopyranosyl)-6-O-(2-O-tartaryl)malonyl)-beta-D-galactopyranoside]-7-O-[6-O-(trans-caffeoyl)-beta-D-glucopyranoside]-3'-O-[beta-D-glucuronopyranoside], and its cyanidin analog as well as delphinidin 3-O-[2-O-(2-O-(trans-caffeoyl)-beta-D-glucopyranosyl)-6-O-(2-O(tartaryl)malonyl)-beta-D-galactopyranoside]-7-O-[6-O-(trans-caffeoyl)-beta-D-glucopyranoside]. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:365 / 373
页数:9
相关论文
共 11 条
  • [1] [Anonymous], 1999, The handbook of natural flavonoids
  • [2] Harborne J B., 1980, Phytochemical Methods -A Guide to Modern Techniques of Plant Analysis, DOI DOI 10.1007/978-94-009-5921-7
  • [3] Harborne J.B., 1967, COMP BIOCH FLAVONOID
  • [4] HEAVENLY BLUE ANTHOCYANIN .4. STRUCTURE DETERMINATION OF HEAVENLY BLUE ANTHOCYANIN, A COMPLEX MONOMERIC ANTHOCYANIN FROM THE MORNING GLORY IPOMOEA-TRICOLOR, BY MEANS OF THE NEGATIVE NOE METHOD
    KONDO, T
    KAWAI, T
    TAMURA, H
    GOTO, T
    [J]. TETRAHEDRON LETTERS, 1987, 28 (20) : 2273 - 2276
  • [5] LAWRENCE WILLIAM JOHN COOPER, 1939, PHIL TRANS ROY SOC LONDON SER B BIOL SCI, V230, P149, DOI 10.1098/rstb.1939.0006
  • [6] CORRELATIONS BETWEEN ANTHOCYANIN TYPE, POLLINATOR AND FLOWER COLOR IN THE LABIATAE
    SAITO, N
    HARBORNE, JB
    [J]. PHYTOCHEMISTRY, 1992, 31 (09) : 3009 - 3015
  • [7] AN ACYLATED CYANIDIN GLYCOSIDE FROM THE RED-PURPLE FLOWERS OF DENDROBIUM
    SAITO, N
    TOKI, K
    UESATO, K
    SHIGIHARA, A
    HONDA, T
    [J]. PHYTOCHEMISTRY, 1994, 37 (01) : 245 - 248
  • [8] Acylated pelargonidin 3,7-glycosides from red flowers of Delphinium hybridum
    Saito, N
    Toki, K
    Suga, A
    Honda, T
    [J]. PHYTOCHEMISTRY, 1998, 49 (03) : 881 - 886
  • [9] Acylated delphinidin glycosides in the blue-violet flowers of Consolida armeniaca
    Saito, N
    Toki, K
    Ozden, S
    Honda, T
    [J]. PHYTOCHEMISTRY, 1996, 41 (06) : 1599 - 1605
  • [10] Two malonylated anthocyanidin glycosides in Ranunculus asiaticus
    Toki, K
    Takeuchi, M
    Saito, N
    Honda, T
    [J]. PHYTOCHEMISTRY, 1996, 42 (04) : 1055 - 1057