Properties and Weldability of Plasticized Polylactic Acid Films

被引:14
|
作者
Stoehr, Neda [1 ]
Baudrit, Benjamin [1 ]
Haberstroh, Edmund [2 ]
Nase, Michael [3 ]
Heidemeyer, Peter [1 ]
Bastian, Martin [1 ]
机构
[1] German Plast Ctr, D-97076 Wurzburg, Germany
[2] Rhein Westfal TH Aachen, Fac Mech Engn, D-52072 Aachen, Germany
[3] Univ Appl Sci Hof, Fac Engn, D-95028 Hof, Germany
关键词
CRYSTALLIZATION; MISCIBILITY; POLY(LACTIDE); BLENDS; PLA; COPOLYMERS;
D O I
10.1002/app.40394
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The objectives of the presented work were to investigate films based on polylactic acid (PLA) and polyethylene glycol (PEG) in order to improve ductility and weldability of PLA films. The effect of plasticizer amount on the thermal, rheological, and mechanical properties of PLA plasticized films was investigated. The PEG content does affect the glass transition and the cold crystallization temperature of PLA in blends, while the melting temperature was not affected by the addition of PEG. The complex viscosity of the neat PLA granules and of plasticized films showed strong temperature and angular velocity dependence. The Young's modulus and tensile strength of plasticized films were improved with increasing plasticizer concentration, while the elongation at break stays rather constant. Plasticized PLA films were furthermore heat welded. These investigations showed that plasticized PLA films can be welded by heat welding. The obtained weld strength is strongly depending on the PEG amount as well as on selected welding parameters. (c) 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40394.
引用
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页数:10
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