Exclusion of impurity particles in charged colloidal crystals

被引:5
作者
Yoshizawa, Koki [1 ]
Toyotama, Akiko [1 ]
Okuzono, Tohru [1 ]
Yamanaka, Junpei [1 ]
机构
[1] Nagoya City Univ, Fac Pharmaceut Sci, Mizuho Ku, Nagoya, Aichi 4678603, Japan
关键词
THERMALLY-INDUCED CRYSTALLIZATION; SOLID-LIQUID TRANSITION; UNIDIRECTIONAL CRYSTALLIZATION; HARD-SPHERE; PHASE-TRANSITIONS; MODEL SYSTEM; GROWTH; KINETICS; SILICA; DISPERSIONS;
D O I
10.1039/c3sm52912f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Uniformly shaped, charged colloidal particles dispersed in water form ordered "crystal" structures when the interaction between the particles is sufficiently strong. Herein, we report the behavior of "impurity" particles, whose sizes and/or charge numbers are different from those of the bulk, on addition to the charged colloidal crystals. These impurities were excluded from the crystals during the homogeneous crystallization, crystal grain growth, and unidirectional crystallization processes. Such systems will be useful as models for studying the refinement of materials and crystal defects.
引用
收藏
页码:3357 / 3361
页数:5
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