Linker-Directed Assembly of Twisted ortho-Phenylene-Based Macrocycles

被引：9
|
作者：
Kinney, Zacharias J. [1 ]
Hartley, C. Scott [1 ]
机构：
[1] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA
来源：
ORGANIC LETTERS | 2018年 / 20卷 / 11期
基金：
美国国家科学基金会;
关键词：
DENSITY-FUNCTIONAL METHODS; CHEMICAL-SHIFTS; FOLDAMERS; RESOLUTION; MOLECULES; CAGES;
D O I：
10.1021/acs.orglett.8b01237
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
o-Phenylene tetramers have been coassembled with linkers into macrocycles through imine condensation. Variation of linker connectivity and length allows both [1 + 1] and [2 + 2] macrocycles to be obtained, complementing (previously reported) [3 + 3] macrocycles. For the [1 + 1] macrocycles, linker length has a clear effect on o-phenylene geometry and macrocycle stability. For the [2 + 2] macrocycles, both homo- and heterochiral configurations are observed, suggesting limited communication of helix handed-ness in these systems.
引用
收藏
页码：3327 / 3331
页数：5
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