Hydroxonium creatininium bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(II) trihydrate

被引：6

作者：

Aghabozorg, Hossein ^{[1
]}

Derikvand, Zohreh ^{[2
]}

Gharamaleki, Jafar Attar

Yousefi, Mohammad ^{[3
]}

机构：

[1] Islamic Azad Univ, Fac Chem, N Tehran Branch, Tehran, Iran

[2] Islamic Azad Univ, Fac Sci, Dept Chem, Khorramabad Branch, Khorramabad, Iran

[3] Islamic Azad Univ, Shahr E Rey Branch, Dept Chem, Tehran, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

ACID;

D O I：

10.1107/S1600536809021837

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, (C4H8N3O)(H3O)[Co(C7H3NO4)(2)]center dot 3H(2)O, contains a protonated creatininium cation, a hydroxonium (H3O)(+) cation, a [Co(pydc)(2)](2-) (pydcH(2) = pyridine-2,6-dicarboxylic acid) complex anion, and three uncoordinated water molecules. The Co-II atom is coordinated by four O and two N atoms from two pydc ligands in a distorted octahedral environment. The structure also contains three uncoordinated water molecules. Extensive intermolecular O-H center dot center dot center dot O, N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds, pi-pi stacking interactions [centroid-centroid distances = 3.565 (14) and 3.425 (14) angstrom] and O center dot center dot center dot pi interactions [O center dot center dot center dot centroid distance = 3.480 (2) angstrom] connect the various components in the crystal structure.

引用

页码：M826 / U1288

页数：14

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