Nanoporous Nanorods Fabricated by Coordination Modulation and Oriented Attachment Growth

被引：632
作者：
Tsuruoka, Takaaki [1 ]
Furukawa, Shuhei [1 ,2 ]
Takashima, Yohei [3 ]
Yoshida, Kaname [4 ]
Isoda, Seiji [4 ]
Kitagawa, Susumu [1 ,2 ,3 ]
机构：
[1] Japan Sci & Technol Agcy JST, ERATO, Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan
[2] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sakyo Ku, Kyoto 6068501, Japan
[3] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
[4] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 26期
关键词：
coordination modes; coordination polymers; crystal growth; nanostructures; METAL-ORGANIC FRAMEWORK; CRYSTAL-GROWTH; NANOCRYSTALS; STORAGE;
D O I：
10.1002/anie.200901177
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A growing attachment: Porous coordination polymer (PCP) nanorods are synthesized by modulation of the coordination equilibria between framework components, which regulates the rate of framework extension and crystal growth. Investigation of the crystal growth mechanism by TEM indicates that face-selective modulation on the surfaces of PCP crystals enhances the anisotropic crystal growth of nanorods by an oriented attachment mechanism. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4739 / 4743
页数：5
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