Biomass-Based N, P, and S Self-Doped Porous Carbon for High Performance Supercapacitors

被引:136
作者
Zhao, Guangzhen [1 ,2 ]
Li, Yanjiang [2 ]
Zhu, Guang [3 ]
Shi, Junyou [1 ,4 ]
Lu, Ting [2 ,5 ]
Pan, Likun [2 ]
机构
[1] Northeast Elect Power Univ, Energy Resources & Power Engn Coll, 169 Changchun Rd, Jilin 132012, Jilin, Peoples R China
[2] East China Normal Univ, Shanghai Key Lab Magnet Resonance, Sch Phys & Mat Sci, 3663 North Zhongshan Rd, Shanghai 200062, Peoples R China
[3] Suzhou Univ, Anhui Key Lab Spin Electron & Nanomat Cultivating, Educ Pk, Suzhou 234000, Peoples R China
[4] Beihua Univ, Forestry Coll, 3999 Binjiang East Rd, Jilin 132013, Jilin, Peoples R China
[5] Shanghai Univ, Sch Environm & Chem Engn, Dept Chem Engn, 99 Shangda Rd, Shanghai 200444, Peoples R China
关键词
Peanut meal; Heteroatom self-doped; Porous carbon; Large specific surface area; Supercapacitors; DOUBLE-LAYER CAPACITANCE; HIGH-ENERGY DENSITY; ELECTRODE MATERIALS; ACTIVATED CARBON; SURFACE-AREA; NITROGEN; NANOSHEETS; POLYHEDRA; CELLULOSE; PSEUDOCAPACITANCE;
D O I
10.1021/acssuschemeng.9b00725
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Biomass-based hierarchically porous carbon is green and eco-friendly, which exhibits a wide potential for energy storage due to its large specific surface area and multiheteroatoms codoping. Herein, nitrogen (N), phosphorus (P), and sulfur (S) self-doped hierarchically porous carbon (N-P-S-HPC) has been prepared by a one-step method from a peanut meal for the first time. The as-prepared N-P-S-HPC possesses a typical hierarchically porous framework (micropores, mesopores, and macropores) with an extremely large specific surface area (2090 m(2) g(-1)) and N (11.2 atomic %), P (0.82 atomic %), and S (0.64 atomic %) doping. N-P-S-HPC as an electrode for supercapacitors displays an ultrahigh specific capacitance of 525 F g(-1) (1 A g(-1)) with the contributions of electrical double layer capacitance (EDLC) and pseudocapacitance (PC). Remarkably, the capacitance retention of N-P-S-HPC reaches up to 68% (10 A g(-1)). The N-P-S-HPC//N-P-S-HPC symmetrical supercapacitor delivers a maximum energy density (24.9 Wh kg(-1) at 400 W kg(-1)). After 6000 cycles at 300 mV s(-1), the capacitance loss is only 10%, indicating excellent cycling stability of the peanut meal converted N-P-S-HPC, which enables it to be a promising candidate for energy storage and renewable delivery devices.
引用
收藏
页码:12052 / 12060
页数:17
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