Synthesis and Initiation Capabilities of Energetic Diazodinitrophenols

被引：11

作者：

Izsak, Daniel ^{[1
]}

Klapoetke, Thomas M. ^{[1
]}

Preimesser, Andreas ^{[1
]}

Stierstorfer, Joerg ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2016年 / 642卷 / 01期

关键词：

Nitrophenols; Diazonium salts; Primary explosives; Structure elucidation;

D O I：

10.1002/zaac.201500703

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diazophenols 3-amino-6-diazo-2, 4-dinitrophenol (4) and 3-chloro-6-diazo-2, 5-dinitrophenol (8) were synthesized and comprehensively characterized. The regio-selectivity of nitration reactions with N,N-(1, 4-phenylene)dimethanesulfonamide (1) and N,N-(1, 4-phenylene)diacetamide (6) was investigated in detail. The purity of the products was confirmed via low temperature X-ray diffraction, multinuclear NMR spectroscopy, and elemental analysis. Moreover, the capability of 4 and 8 to initiate RDX (1, 3, 5-trinitro-1, 3, 5-triazinane) was tested, together with the two other recently presented diazophenols 4-diazo-2, 6-dinitrophenol (iso-DDNP) and 3-hydroxy-DDNP (HODDNP). The tests revealed superior properties of HODDNP compared to DDNP and the other tested diazophenols regarding its ability to initiate RDX.

引用

页码：48 / 55

页数：8

共 25 条

[1]

Agrawal J. P., 2010, HIGH ENERGY MAT, P85

[2]

Ahmad SR, 2015, LASER IGNITION OF ENERGETIC MATERIALS, P1

[3] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[4]

[Anonymous], 2002, WIWEB-Standardarbeitsanweisung 4-5.1.02, Ermittlung der Explosionsgefahrlichkeit, hier der Schlagempfindlichkeit mit dem Fallhammer

[5]

[Anonymous], 2009, CRYSALIS PRO

[6]

[Anonymous], 2002, WIWEB-Standardarbeitsanweisung 4-5.1.03, Ermittlung Der Explosionsgerfa

[7] Primer compositions in the course of time: From black powder and SINOXID to SINTOX compositions and SINCO booster [J].

Brede, U ;

Hagel, R ;

Redecker, KH ;

Weuter, W .

PROPELLANTS EXPLOSIVES PYROTECHNICS, 1996, 21 (03) :113-117

[8] SYNTHESIS OF ISOMERIC DINITRO-PARA-PHENYLENEDIAMINES BY NITRATION OF NN'-BIS(PHENYLSULPHONYL)-PARA-PHENYLENEDIAMINE [J].

CHU, KY ;

GRIFFITHS, J .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1978, (05) :406-408

[9]

Farrugia L.J., 1999, J. Appl. Crystallogr, V32, P837, DOI [10.1107/S0021889899006020, DOI 10.1107/S0021889812029111, 10.1107/S0021889812029111]

[10] Potassium 1,1′-Dinitramino-5,5′-bistetrazolate: A Primary Explosive with Fast Detonation and High Initiation Power [J].

Fischer, Dennis ;

Klapoetke, Thomas M. ;

Stierstorfer, Joerg .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (31) :8172-8175

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