Characterization of aggregate state of polydisperse ferrofluids: Some aspects of anisotropy analysis of 2D SAXS in magnetic field

被引:11
作者
Veligzhanin, A. A. [1 ]
Frey, D. I. [2 ]
Shulenina, A. V. [1 ,3 ]
Gruzinov, A. Yu. [4 ]
Zubavichus, Ya. V. [1 ]
Avdeev, M. V. [3 ,5 ]
机构
[1] Natl Res Ctr, Kurchatov Inst, Moscow, Russia
[2] RAS, Shirshov Inst Oceanol, Moscow, Russia
[3] Lomonosov Moscow State Univ, Fac Phys, Moscow, Russia
[4] DESY, EMBL, Hamburg, Germany
[5] Joint Inst Nucl Res, Dubna, Moscow Reg, Russia
关键词
Ferrofluids; Magnetic fluids; Small-angle scattering; Dipole-dipole interaction; Dipolar fluids; Aggregation; SMALL-ANGLE NEUTRON; X-RAY-SCATTERING; RADIATION; DYNAMICS; SYSTEMS;
D O I
10.1016/j.jmmm.2017.10.052
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
2D small-angle X-ray scattering (SAXS) patterns for dilute ferrofluids with different degree of particle interaction under external magnetic field are analyzed to obtain structural characteristics of aggregates formed by polydisperse particles. Classical ferrofluids based on organic low-polarity solvents (toluene, decalin) with dispersed nanoparticles of magnetite and cobalt coated with oleic acid and water-based ferrofluid with dispersed magnetite nanoparticles coated with double layer of sodium oleate, are studied. All systems show the Langevin type behavior regarding the orientation of the anisotropic aggregates in them with the saturation at a relatively weak magnetic field strength. The field-induced anisotropy in the SAXS patterns is considered in the frame of a simple approximation. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:285 / 289
页数:5
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