Stereoselective synthesis of (Z)-β-arylvinyl bromides from anti-2,3-dibromo-3-arylpropanoic acids

被引：1

作者：

Xv, Wenjing ^{[1
]}

Zhang, Wensheng ^{[1
]}

Zhang, Fei ^{[2
]}

Kuang, Chunxiang ^{[3
]}

机构：

[1] Jiaozuo Teachers Coll, Sch Sci, Jiaozuo 450001, Peoples R China

[2] Jiaozuo Vocat Educ Ctr, Jiaozuo 454001, Peoples R China

[3] Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2014年 / 02期

基金：

中国国家自然科学基金;

关键词：

stereoselective synthesis; (Z)-beta-arylvinyl bromide; decarboxylation; NaN3; ONE-POT SYNTHESIS; MICROWAVE-INDUCED REACTION; CROSS-COUPLING REACTIONS; STEREOSPECIFIC SYNTHESIS; VINYLIC ORGANOBORANES; ALKENYL HALIDES; CONVENIENT; (Z)-1-BROMO-1-ALKENES; (Z)-1-HALO-1-ALKENES; VINYLSILANES;

D O I：

10.3184/174751914X13896335381533

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel method for the stereoselective synthesis of (Z)-beta-arylvinyl bromides in excellent yields by debrominative decarboxylation of anti-2,3-dibromo-3-arylpropanoic acids using NaN3 was developed. This facile transformation was achieved under room temperature for 1-2 h.

引用

页码：115 / 117

页数：3

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