Density and viscosity of ternary liquid mixtures of pyridine with same polar and non-polar solvents at 303.15 K

被引:0
|
作者
Maheshwari, G [1 ]
Singh, M [1 ]
机构
[1] Agra Coll, Dept Chem, Agra 282002, Uttar Pradesh, India
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Density and viscosity of ternary liquid mixtures of pyridine with some polar (acetone and methyl ethyl ketone) and non-polar (benzene, toluene and carbon tetrachloride) solvents have been measured as a function of the composition and at a constant temperature 303.15 K. Various excess thermodynamic functions, viz. excess viscosity (eta(E)), excess volume (V-E), excess Gibbs free energy of activation of flow (DeltaG(not equalE)) and the values of interaction parameter d in Grunberg and Nissan equation have been calculated as a function of composition of ternary mixtures. The results have been interpreted in terms of molecular interactions existing between the components of these mixtures.
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页码:659 / 664
页数:6
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