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Visible-Light Photocatalysts of ZrO2/AgCl:Eu3+ Nanoparticles
被引:4
作者:
Pham Van Huan
[1
]
Phuong Dinh Tam
[1
,2
]
Vuong-Hung Pham
[1
]
机构:
[1] HUST, AIST, 01 Dai Co Viet Rd, Hanoi, Vietnam
[2] Phenikaa Univ, Fac Mat Sci & Engn, Hanoi 1000, Vietnam
关键词:
Zirconia;
luminescence;
precipitation;
quenching;
photocatalyst;
nanoparticles;
PHOTOLUMINESCENCE;
NANOSTRUCTURES;
DEGRADATION;
EMISSION;
GLASSES;
ZRO2;
EU;
AG;
D O I:
10.1007/s11664-019-07337-w
中图分类号:
TM [电工技术];
TN [电子技术、通信技术];
学科分类号:
0808 ;
0809 ;
摘要:
This paper reports the visible-light photocatalysts and luminescence quenching of ZrO2/AgCl:Eu3+ nanoparticles synthesized by the co-precipitation method as a function of AgCl concentration. XRD analysis indicated the presence of crystalline tetragonal ZrO2 and an AgCl phase. The synthesized ZrO2/AgCl:Eu3+ nanoparticles were observed to have a spherical morphology with diameters of approximate to 20nm. The photocatalyst with 2.5% mole fractions of AgCl showed effective degradation of methylene blue under visible light with the decolorization percentage reaching approximate to 95% in 180min. The red emission of Eu3+ in the ZrO2/AgCl:Eu3+ nanoparticles decreased with increasing AgCl mole fraction. Visible-light photocatalysts of ZrO2/AgCl:Eu3+ nanoparticles can be attributed to the presence of AgCl resulting in higher photoexcited charges separation, which can be confirmed by lower luminescence intensity.
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页码:5294 / 5300
页数:7
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