Effects of Ionic Liquids for Lipase-Catalyzed Chiral 1,1′-binaphthyl-2-yl(phenyl)methanone O-acetyl Oxime Synthesis

被引：1

作者：

Zhou, Yongchang ^{[1
,2
]}

Takahashi, Motohiro ^{[1
,2
]}

Aoyagi, Naoto ^{[2
]}

Li, Chunlei ^{[2
]}

Kijima, Tatsuro ^{[2
]}

Izumi, Taeko ^{[2
]}

机构：

[1] Yonezawa Hamari Chem Ltd, Dept Technol, Yonezawa, Yamagata 9921128, Japan

[2] Yamagata Univ, Grad Sch Sci & Engn, Yonezawa, Yamagata 9928510, Japan

来源：

LETTERS IN ORGANIC CHEMISTRY | 2009年 / 6卷 / 04期

关键词：

Ionic liquids; Lipase-catalyzed; Chiral; O-acetyl oxime; Synthesis; Resolution; ENZYME;

D O I：

10.2174/157017809788489864

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The resolution of 1,1'-binaphthyl-2-yl(phenyl) methanone O-acetyl oxime catalyzed by lipase in three different ionic liquids, 1-butyl-3-methylimidazolium hexafluoride-phosphate, [bmim][PF6], 1-butyl-3-methylimidazolium tetrafluoroborate, [bmim][BF4] and N-butyl-pyridium hexafluorophosphate, [BuPy][PF6] and organic solvents was studied. The lipase shows low activity in ionic liquids and organic solvent with ionic liquids as the additive, while the lipase coated with ionic liquids gives the best enantioselectivity as high as 95%

引用

页码：297 / 300

页数：4

共 49 条

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