Influence of different electron acceptors in organic sensitizers on the performance of dye-sensitized solar cells

被引:25
作者
Yu, Xiaoqiang [1 ]
Ci, Zhenhua [1 ]
Liu, Teng [1 ]
Feng, Xiujuan [1 ]
Wang, Chaolei [1 ]
Ma, Tingli [1 ]
Bao, Ming [1 ]
机构
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116023, Peoples R China
基金
中国国家自然科学基金;
关键词
Dye-sensitized solar cells; Sensitizers; Electron acceptors; Cyanoacrylic acid; Photovoltaic properties; Solar-to-electrical energy conversion; BAND-GAP CHROMOPHORES; HIGHLY EFFICIENT; CONJUGATED UNIT; INDOLINE DYES; COUMARIN DYES; LIGHT; OXIDE; PHOTOVOLTAICS; CONVERSION; LIQUID;
D O I
10.1016/j.dyepig.2013.10.045
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Five kinds of triphenylamine-based organic dyes with different electron acceptors were designed and synthesized as sensitizers for dye-sensitized solar cells (DSSCs). The photophysical and electrochemical properties of these dyes were investigated and their performance as sensitizers in DSSCs was measured. The dye with cyanoacrylic acid electron acceptor exhibits the highest solar-to-electrical energy conversion efficiency of 4.93% (short-circuit photocurrent density J(sc) = 8.59 mA cm(-2), open-circuit photovoltage V-oc = 0.77 V, and fill factor ff = 0.75) under 100 mW cm(-2)-simulated AM 1.5 G solar irradiation. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:126 / 132
页数:7
相关论文
共 56 条
[1]   Structure-property relationship of different electron donors: novel organic sensitizers based on fused dithienothiophene π-conjugated linker for high efficiency dye-sensitized solar cells [J].
Akhtaruzzaman, Md. ;
Menggenbateer ;
Islam, Ashraful ;
El-Shafei, Ahmed ;
Asao, Naoki ;
Jin, Tienan ;
Han, Liyuan ;
Alamry, Khalid A. ;
Kosa, Samia A. ;
Asiri, Abdullah Mohamed ;
Yamamoto, Yoshinori .
TETRAHEDRON, 2013, 69 (16) :3444-3450
[2]   A novel metal-free panchromatic TiO2 sensitizer based on a phenylenevinylene-conjugated unit and an indoline derivative for highly efficient dye-sensitized solar cells [J].
Akhtaruzzaman, Md ;
Islam, Ashraful ;
Yang, Fan ;
Asao, Naoki ;
Kwon, Eunsang ;
Singh, Surya Prakash ;
Han, Liyuan ;
Yamamoto, Yoshinori .
CHEMICAL COMMUNICATIONS, 2011, 47 (45) :12400-12402
[3]   Novel Quinoxaline-Based Organic Sensitizers for Dye-Sensitized Solar Cells [J].
Chang, Dong Wook ;
Lee, Hyo Joong ;
Kim, Jong H. ;
Park, Soo Young ;
Park, Su-Moon ;
Dai, Liming ;
Baek, Jong-Beom .
ORGANIC LETTERS, 2011, 13 (15) :3880-3883
[4]   Structurally Simple Dipolar Organic Dyes Featuring 1,3-Cyclohexadiene Conjugated Unit for Dye-Sensitized Solar Cells [J].
Chen, Kuan-Fu ;
Hsu, Ying-Chan ;
Wu, Qiongyou ;
Yeh, Ming-Chang P. ;
Sun, Shih-Sheng .
ORGANIC LETTERS, 2009, 11 (02) :377-380
[5]   Highly efficient and thermally stable organic sensitizers for solvent-free dye-sensitized solar cells [J].
Choi, Hyunbong ;
Baik, Chul ;
Kang, Sang Ook ;
Ko, Jaejung ;
Kang, Moon-Sung ;
Nazeeruddin, Md. K. ;
Graetzel, Michael .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (02) :327-330
[6]   Novel organic dyes containing bis-dimethylfluorenyl amino benzo[b]thiophene for highly efficient dye-sensitized solar cell [J].
Choi, Hyunbong ;
Lee, Jae Kwan ;
Song, Kihyung ;
Kang, Sang Ook ;
Ko, Jaejung .
TETRAHEDRON, 2007, 63 (15) :3115-3121
[7]   Novel thiophene-conjugated indoline dyes for zinc oxide solar cells [J].
Dentani, Takuya ;
Kubota, Yasuhiro ;
Funabiki, Kazumasa ;
Jin, Jiye ;
Yoshida, Tsukasa ;
Minoura, Hideki ;
Miura, Hidetoshi ;
Matsui, Masaki .
NEW JOURNAL OF CHEMISTRY, 2009, 33 (01) :93-101
[8]  
Frisch M., 2004, GAUSSIAN 03 REVISION, DOI DOI 10.1016/J.MOLSTRUC.2017.03.014
[9]   Enhance the optical absorptivity of nanocrystalline TiO2 film with high molar extinction coefficient ruthenium sensitizers for high performance dye-sensitized solar cells [J].
Gao, Feifei ;
Wang, Yuan ;
Shi, Dong ;
Zhang, Jing ;
Wang, Mingkui ;
Jing, Xiaoyan ;
Humphry-Baker, Robin ;
Wang, Peng ;
Zakeeruddin, Shaik M. ;
Graetzel, Michael .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (32) :10720-10728
[10]   Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells [J].
Grätzel, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 164 (1-3) :3-14