Low-temperature synthesis of high-ordered anatase TiO2 nanotube array films coated with exposed {001} nanofacets

被引:37
作者
Ding, Jie [1 ]
Huang, Zhennan [1 ,2 ]
Zhu, Jihao [3 ]
Kou, Shengzhong [2 ]
Zhang, Xiaobin [1 ]
Yang, Hangsheng [1 ]
机构
[1] Zhejiang Univ, Sch Mat Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
[2] Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
[3] State Ocean Adm, Inst Oceanog 2, Hangzhou 310012, Zhejiang, Peoples R China
关键词
NANOSIZED ANATASE; SINGLE-CRYSTALS; HIGH PERCENTAGE; FACETS; DEGRADATION; EFFICIENCY; NANOSHEETS; GROWTH;
D O I
10.1038/srep17773
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
High-ordered anatase TiO2 nanotube array films coated with exposed high-reactive {001} nanofacets were fabricated by a modified hydrothermal method using amorphous anodic TiO2 nanotube arrays (ATONAs) as starting materials. It was found that the reaction between gas phase HF and solid ATONAs played a key role in the transformation process from amorphous to anatase TiO2, and the TiO2 tubular structure kept unchanged during the surface modification with an exposed {001} facets up to 76.5%, which could be attributed to the low reaction temperature of 130 degrees C. Our study provided a novel route for the facile preparation of {001} facets exposed anatase TiO2.
引用
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页数:7
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