Low-temperature synthesis of high-ordered anatase TiO2 nanotube array films coated with exposed {001} nanofacets

被引:37
作者
Ding, Jie [1 ]
Huang, Zhennan [1 ,2 ]
Zhu, Jihao [3 ]
Kou, Shengzhong [2 ]
Zhang, Xiaobin [1 ]
Yang, Hangsheng [1 ]
机构
[1] Zhejiang Univ, Sch Mat Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
[2] Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
[3] State Ocean Adm, Inst Oceanog 2, Hangzhou 310012, Zhejiang, Peoples R China
来源
SCIENTIFIC REPORTS | 2015年 / 5卷
关键词
NANOSIZED ANATASE; SINGLE-CRYSTALS; HIGH PERCENTAGE; FACETS; DEGRADATION; EFFICIENCY; NANOSHEETS; GROWTH;
D O I
10.1038/srep17773
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
High-ordered anatase TiO2 nanotube array films coated with exposed high-reactive {001} nanofacets were fabricated by a modified hydrothermal method using amorphous anodic TiO2 nanotube arrays (ATONAs) as starting materials. It was found that the reaction between gas phase HF and solid ATONAs played a key role in the transformation process from amorphous to anatase TiO2, and the TiO2 tubular structure kept unchanged during the surface modification with an exposed {001} facets up to 76.5%, which could be attributed to the low reaction temperature of 130 degrees C. Our study provided a novel route for the facile preparation of {001} facets exposed anatase TiO2.
引用
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页数:7
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共 38 条
[1]   Effect of heat treatment on the crystal phase composition, semiconducting properties and photoelectrocatalytic color removal efficiency of TiO2 nanotubes arrays [J].
Acevedo-Pena, Prospero ;
Carrera-Crespo, J. Edgar ;
Gonzalez, Federico ;
Gonzalez, Ignacio .
ELECTROCHIMICA ACTA, 2014, 140 :564-571
[2]   Enhanced nitrogen doping in TiO2 nanoparticles [J].
Burda, C ;
Lou, YB ;
Chen, XB ;
Samia, ACS ;
Stout, J ;
Gole, JL .
NANO LETTERS, 2003, 3 (08) :1049-1051
[3]   Visible light induced photocatalytic degradation of organic pollutants [J].
Chatterjee, D ;
Dasgupta, S .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2005, 6 (2-3) :186-205
[4]   Titanium dioxide nanomaterials: Synthesis, properties, modifications, and applications [J].
Chen, Xiaobo ;
Mao, Samuel S. .
CHEMICAL REVIEWS, 2007, 107 (07) :2891-2959
[5]   ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].
FUJISHIMA, A ;
HONDA, K .
NATURE, 1972, 238 (5358) :37-+
[6]   Reactivity of anatase TiO2 nanoparticles:: The role of the minority (001) surface [J].
Gong, XQ ;
Selloni, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (42) :19560-19562
[7]   One-step synthesis of Ag-Fe3O4 nanocomposites and their SERS properties [J].
Guo, Hongyan ;
Zhao, Aiwu ;
Gao, Qian ;
Li, Da ;
Zhang, Maofeng ;
Gan, Zibao ;
Wang, Dapeng ;
Tao, Wenyu ;
Chen, Xucheng .
JOURNAL OF NANOPARTICLE RESEARCH, 2014, 16 (08)
[8]   Photocatalytic Reduction of CO2 on TiO2 and Other Semiconductors [J].
Habisreutinger, Severin N. ;
Schmidt-Mende, Lukas ;
Stolarczyk, Jacek K. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (29) :7372-7408
[9]   Dominant Factors Governing the Rate Capability of a TiO2 Nanotube Anode for High Power Lithium Ion Batteries [J].
Han, Hyungkyu ;
Song, Taeseup ;
Lee, Eung-Kwan ;
Devadoss, Anitha ;
Jeon, Yeryung ;
Ha, Jaehwan ;
Chung, Yong-Chae ;
Choi, Young-Min ;
Jung, Yeon-Gil ;
Paik, Ungyu .
ACS NANO, 2012, 6 (09) :8308-8315
[10]   Synthesis of Titania Nanosheets with a High Percentage of Exposed (001) Facets and Related Photocatalytic Properties [J].
Han, Xiguang ;
Kuang, Qin ;
Jin, Mingshang ;
Xie, Zhaoxiong ;
Zheng, Lansun .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (09) :3152-+