Plasma Electrochemical Synthesis of Graphene-Phosphorene Composite and Its Catalytic Activity towards Hydrogen Evolution Reaction

被引:2
作者
Kochergin, Valeriy K. [1 ]
Komarova, Natal'ya S. [1 ]
Kotkin, Alexander S. [1 ]
Manzhos, Roman A. [1 ]
Vasiliev, Vladimir P. [1 ]
Krivenko, Alexander G. [1 ]
机构
[1] Russian Acad Sci, Fed Res Ctr Problems Chem Phys & Med Chem, Chernogolovka 142432, Russia
来源
C-JOURNAL OF CARBON RESEARCH | 2022年 / 8卷 / 04期
基金
俄罗斯科学基金会;
关键词
phosphorene; few-layer graphene structures; electrolytic plasma; electrochemical exfoliation of graphite; hydrogen evolution reaction; LAYERED BLACK PHOSPHORUS; EXFOLIATION; GRAPHITE; OXIDE; REDUCTION; ECONOMY;
D O I
10.3390/c8040079
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
For the first time, graphene-phosphorene structures were synthesized using the plasma-assisted electrochemical method. The catalytic activity of the composite obtained in the electrolytic plasma mode and its mixtures with few-layer graphene structures toward the hydrogen evolution reaction was studied. A substantial increase in the catalytic activity of the phosphorene structures towards the hydrogen evolution reaction was realized by mixing them with few-layer graphene structures. The catalyst demonstrates excellent activity towards the hydrogen evolution reaction in alkaline media with a low overpotential of 940 mV at a current density of 10 mA center dot cm(-2) and a small Tafel slope of 130 mV dec(-1).
引用
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页数:8
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