A safe and superior propylene carbonate-based electrolyte with high-concentration Li salt

被引:16
作者
Ding, Yuanlei [1 ]
Yun, Jiaojiao [1 ]
Liu, Hongmei [1 ]
Wan, Zhongming [1 ]
Shen, Ming [2 ]
Zhang, Li [1 ]
Qu, Qunting [1 ]
Zheng, Honghe [1 ]
机构
[1] Soochow Univ, Sch Energy, Suzhou 215006, Jiangsu, Peoples R China
[2] Huasheng Chem Corp, Zhangjiagang 215635, Jiangsu, Peoples R China
关键词
electrochemistry; electrolytes; energy conversion; high concentration; Li-ion batteries; NMS-IX; propylene carbonate; safety; LITHIUM-ION BATTERIES; NON-FLAMMABLE ELECTROLYTE; PC-BASED ELECTROLYTES; HIGH-ENERGY DENSITY; GRAPHITE ANODE; ELECTROCHEMICAL INTERCALATION; NATURAL GRAPHITE; SEI FORMATION; PERFORMANCE; LIQUIDS;
D O I
10.1515/pac-2013-1120
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrolytes play an essential role in determining the safety and electrochemical performance of Li-ion batteries. This work reported a propylene carbonate-based electrolyte with high-concentration Li salt. The fire-retardancy test and thermogravimetric analysis showed that this electrolyte is of high safety. In addition, this electrolyte exhibited superior electrochemical performance as compared with the commercial electrolyte in case of reversible capacity, rate behavior, and cycling stability.
引用
收藏
页码:585 / 591
页数:7
相关论文
共 32 条
[1]   Correlation between cointercalation of solvents and electrochemical intercalation of lithium into graphite in propylene carbonate solution [J].
Abe, T ;
Kawabata, N ;
Mizutani, Y ;
Inaba, M ;
Ogumi, Z .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (03) :A257-A261
[2]   GBL-based electrolyte for Li-ion battery: thermal and electrochemical performance [J].
Belov, Dmitry ;
Shieh, Deng-Tswen .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2012, 16 (02) :603-615
[3]   Origin of graphite exfoliation - An investigation of the important role of solvent cointercalation [J].
Chung, GC ;
Kim, HJ ;
Yu, SI ;
Jun, SH ;
Choi, JW ;
Kim, MH .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (12) :4391-4398
[4]   Ionic liquids as electrolytes [J].
Galinski, Maciej ;
Lewandowski, Andrzej ;
Stepniak, Izabela .
ELECTROCHIMICA ACTA, 2006, 51 (26) :5567-5580
[5]   The role of carbonate solvents on lithium intercalation into graphite [J].
Gnanaraj, J. S. ;
Thompson, R. W. ;
DiCarlo, J. F. ;
Abraham, K. M. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (03) :A185-A191
[6]   Improved electrolytes for Li-ion batteries: Mixtures of ionic liquid and organic electrolyte with enhanced safety and electrochemical performance [J].
Guerfi, A. ;
Dontigny, M. ;
Charest, P. ;
Petitclerc, M. ;
Lagace, M. ;
Vijh, A. ;
Zaghib, K. .
JOURNAL OF POWER SOURCES, 2010, 195 (03) :845-852
[7]   Characterisation of the SEI formed on natural graphite in PC-based electrolytes [J].
Herstedt, M ;
Andersson, AM ;
Rensmo, H ;
Siegbahn, H ;
Edström, K .
ELECTROCHIMICA ACTA, 2004, 49 (27) :4939-4947
[8]   Macroporous LiFePO4 as a cathode for an aqueous rechargeable lithium battery of high energy density [J].
Hou, Yuyang ;
Wang, Xujiong ;
Zhu, Yusong ;
Hu, Chenglin ;
Chang, Zheng ;
Wu, Yuping ;
Holze, Rudolf .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (46) :14713-14718
[9]   Electrochemical intercalation of lithium ion within graphite from propylene carbonate solutions [J].
Jeong, SK ;
Inaba, M ;
Iriyama, Y ;
Abe, T ;
Ogumi, Z .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (01) :A13-A15
[10]   Surface film formation on a graphite negative electrode in lithium-ion batteries: Atomic force microscopy study on the effects of film-forming additives in propylene carbonate solutions [J].
Jeong, SK ;
Inaba, M ;
Mogi, R ;
Iriyama, Y ;
Abe, T ;
Ogumi, Z .
LANGMUIR, 2001, 17 (26) :8281-8286