The functionalized ionic liquid-stabilized palladium nanoparticles catalyzed selective hydrogenation in ionic liquid

被引：51

作者：

Hu, Yu ^{[1
]}

Yang, Hanming ^{[2
,3
]}

Zhang, Yingchao ^{[1
]}

Hou, Zhenshan ^{[1
]}

Wang, Xiangrui ^{[1
]}

Qiao, Yunxiang ^{[1
]}

Li, Huan ^{[1
]}

Feng, Bo ^{[1
]}

Huang, Qingfa ^{[1
]}

机构：

[1] E China Univ Sci & Technol, Key Lab Adv Mat, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China

[2] S Cent Univ Nationalities, Key Lab Catalysis & Mat Sci State Ethn Affairs Co, Wuhan 430074, Peoples R China

[3] S Cent Univ Nationalities, Minist Educ, Wuhan 430074, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2009年 / 10卷 / 14期

基金：

中国国家自然科学基金;

关键词：

Functionalized ionic liquid; Palladium nanoparticles; Selective hydrogenation; CHEMOSELECTIVE HYDROGENATION; CARBON NANOTUBES; ALCOHOL; LIGANDS; PD/C;

D O I：

10.1016/j.catcom.2009.06.025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The functionalized ionic liquid (2,3-dimethyl-l-[3-N,N-bis(2-pyridyl)-propylamido] imidazolium hexafluorophosphate, [BMMDPA][PF6]) stabilized and modified palladium nanoparticles were obtained by reducing palladium(II) complex with molecular hydrogen. The as-synthesized palladium nanoparticles have been characterized by different methods. It was demonstrated that the Pd nanoparticles were very efficient catalysts for the selective hydrogenation of the C=C bonds of various functionalized alkenes under mild conditions in neat ionic liquid (1-n-butyl-2,3-dimethylimidazolium hexafluorophosphate, [BMMIM][PF6]). An efficient separation of the products from reaction mixture (ionic liquid phase) was realized and the catalyst's nano-dispersion and high performance could be preserved. (c) 2009 Elsevier B.V. All rights reserved.

引用

页码：1903 / 1907

页数：5

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