(Sulfur,nitrogen)-codoped rutile-titanium dioxide as a visible-light-activated photocatalyst

被引：93
作者：
Liu, HY [1 ]
Gao, L [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
来源：
JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2004年 / 87卷 / 08期
关键词：
D O I：
10.1111/j.1551-2916.2004.01582.x
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Many elements have been used to dope titanium dioxide (TiO2) so that it absorbs light in the visible region of the solar spectrum. We have synthesized, for the first time, (S,N)codoped rutile-TiO2 photocatalyst using a hydrothermal method and subsequent nitridation under NH3 flow. The (S,N)-codoping causes the absorption edge of TiO2 to be shifted to the longer-wavelength region and two optical absorption bandgaps in the visible-light region. (S,N)-codoping has a better photocatalytic activity than S-doping and N-doping for degradation of methylene blue solution under visible light.
引用
收藏
页码：1582 / 1584
页数：3
相关论文
共 27 条
  • [1] Visible-light photocatalysis in nitrogen-doped titanium oxides
    Asahi, R
    Morikawa, T
    Ohwaki, T
    Aoki, K
    Taga, Y
    [J]. SCIENCE, 2001, 293 (5528) : 269 - 271
  • [2] HYDROTHERMAL PREPARATION OF UNIFORM NANOSIZE RUTILE AND ANATASE PARTICLES
    CHENG, HM
    MA, JM
    ZHAO, ZG
    QI, LM
    [J]. CHEMISTRY OF MATERIALS, 1995, 7 (04) : 663 - 671
  • [3] THE ROLE OF METAL-ION DOPANTS IN QUANTUM-SIZED TIO2 - CORRELATION BETWEEN PHOTOREACTIVITY AND CHARGE-CARRIER RECOMBINATION DYNAMICS
    CHOI, WY
    TERMIN, A
    HOFFMANN, MR
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (51) : 13669 - 13679
  • [4] Investigations of metal-doped titanium dioxide photocatalysts
    Dvoranová, D
    Brezová, V
    Mazúr, M
    Malati, MA
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 37 (02) : 91 - 105
  • [5] Photocatalytic mineralisation of methylene blue using buoyant TiO2-coated polystyrene beads
    Fabiyi, ME
    Skelton, RL
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2000, 132 (1-2) : 121 - 128
  • [6] Fujishima A., 2000, J PHOTOCH PHOTOBIO C, V1, P1, DOI DOI 10.1016/S1389-5567(00)00002-2
  • [7] Preparation and characterizations of Fe- or Ni-substituted titania nanosheets as photocatalysts
    Harada, M
    Sasaki, T
    Ebina, Y
    Watanabe, M
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 148 (1-3) : 273 - 276
  • [8] A promoting effect of NH4F addition on the photocatalytic activity of sol-gel TiO2 films
    Hattori, A
    Yamamoto, M
    Tada, H
    Ito, S
    [J]. CHEMISTRY LETTERS, 1998, (08) : 707 - 708
  • [9] Carbon-doped anatase TiO2 powders as a visible-light sensitive photocatalyst
    Irie, H
    Watanabe, Y
    Hashimoto, K
    [J]. CHEMISTRY LETTERS, 2003, 32 (08) : 772 - 773
  • [10] Nitrogen-concentration dependence on photocatalytic activity of TiO2-xNx powders
    Irie, H
    Watanabe, Y
    Hashimoto, K
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (23) : 5483 - 5486
123