Total synthesis of prelaureatin

被引：0

作者：

Fujiwaraa, K ^{[1
]}

Souma, SI ^{[1
]}

Mishima, H ^{[1
]}

Murai, A ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan

来源：

SYNLETT | 2002年 / 09期

关键词：

total synthesis; stereoselective synthesis; natural products; ethers; metathesis;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Total synthesis of prelaureatin, which is an 8-membered cyclic ether isolated from red alga Laurencia nipponica, has been achieved through a process including stereoselective introduction of two allyl groups starting from galactose pentaacetate, cleavage of the hexose ring, and transformation of an acyclic triene into an oxocene by selective ring-closing metathesis.

引用

页码：1493 / 1495

页数：3

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