Novel Propylene Production Route: Utilizing Hydrotreated Shale Oil as Feedstock via Two-Stage Riser Catalytic Cracking

被引:12
作者
Chen, Xiaobo [1 ]
Li, Nan [1 ]
Yang, Yiqing [2 ]
Yang, Chaohe [1 ]
Shan, Honghong [1 ]
机构
[1] China Univ Petr, State Key Lab Heavy Oil Proc, Qingdao 266580, Shandong, Peoples R China
[2] PetroChina, Lanzhou Petrochem Res Ctr, Lanzhou 730060, Gansu, Peoples R China
基金
中国国家自然科学基金;
关键词
RESONANCE MASS-SPECTROMETRY; ELECTROSPRAY-IONIZATION ESI; LIGHT OLEFINS; NITROGEN-COMPOUNDS; FCC PROCESS; ZEOLITES; YIELD;
D O I
10.1021/acs.energyfuels.5b02076
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this paper; a novel propylene production route is proposed, Hydrotreated shale oil was first used as,a feedstock for fluid catalytic cracking (FCC) to increase the propylene yield because of its abundant aliphatic hydrocarbons. The catalytic cracking performance of hydrotreated shale oil,was investigated in detail via two-stage riser catalytic cracking (TMP). The results of the pilot-plant-scale TMP indicated that hydrotreated shale oil blended with 30 wt % Daqing vacuum residue could not only maximize the propylene yield but also showed a more desirable product distribution than conventional FCC feedstock. The yield:: of liquid products (including liquefied petroleum gas, gasoline, and diesel) was as high as 84.93 wt %, and the propylene yield reached 23.62 wt %, whereas the dry gas yield was only 6.06 wt %. This study may provideia novel route to reasonably use shale oil.
引用
收藏
页码:7190 / 7195
页数:6
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