Facile Cycling of Ti-Doped LiAlH4 for High Performance Hydrogen Storage

被引：94

作者：

Liu, Xiangfeng ^{[1
]}

McGrady, G. Sean ^{[1
]}

Langmi, Henrietta W. ^{[1
]}

Jensen, Craig M. ^{[2
]}

机构：

[1] Univ New Brunswick, Dept Chem, Fredericton, NB E3B 5A3, Canada

[2] Univ Hawaii Manoa, Dept Chem, Honolulu, HI 96822 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 14期

基金：

加拿大自然科学与工程研究理事会;

关键词：

COMPLEX HYDRIDES; METAL; DEHYDROGENATION; DESORPTION;

D O I：

10.1021/ja809917g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

LiH and Ti-doped At react quantitatively with H-2 in Me2O solution to form LiAlH4 under mild conditions. The solvent is easily vented along with excess H-2 on completion, leaving dry Ti-doped LiAlH4; this releases similar to 7 wt % H-2 commencing at 80 degrees C with excellent kinetics.

引用

页码：5032 / +

页数：3

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