Influence of cyclodextrin and its glucose units on polymerization of styrene

被引：10

作者：

Hu, J ^{[1
]}

Li, SJ ^{[1
]}

Wang, DQ ^{[1
]}

Liu, BL ^{[1
]}

机构：

[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China

来源：

POLYMER INTERNATIONAL | 2004年 / 53卷 / 07期

关键词：

cyclodextrins; glucose units; polymerization; polymer particles;

D O I：

10.1002/pi.1502

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The free radical polymerization of styrene in water in the presence of beta-cyclodextrin (beta-CD) without using surfactants is described. The effect of beta-CD which greatly accelerated the polymerization, was wholly contributed to the formation of host-guest complexes with hydrophobic monomer to increase the monomer solubility in water. Through adding toluene that is similar in structure to monomer styrene to block the formation of beta-CD with styrene monomer, we found that just like free glucose, the glucose units of beta-CD could also accelerate the polymerization. The polymer particles with narrow particle-size distribution and clear surface were prepared without using any surfactants and solvent mixtures. (C) 2004 Society of Chemical Industry.

引用

页码：1003 / 1006

页数：4

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