Synthesis of nanocrystalline titanium nitride at low temperature and its thermal stability

被引：35

作者：

Ma, Jianhua ^{[1
,2
]}

Wu, Meining ^{[1
]}

Du, Yihong ^{[3
]}

Chen, Suqin ^{[1
]}

Li, Guoxing ^{[1
]}

Hu, Jianbo ^{[1
]}

机构：

[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325027, Zhejiang, Peoples R China

[2] Wenzhou Univ, Nanomat & Chem Key Lab, Adv Mat Res Ctr Wenzhou, Wenzhou 325027, Zhejiang, Peoples R China

[3] Wenzhou Univ, City Coll, Wenzhou 325027, Zhejiang, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2009年 / 476卷 / 1-2期

关键词：

Nanostructured materials; Titanium nitride; Chemical synthesis; X-ray diffraction; Thermal analysis; CHEMICAL-VAPOR-DEPOSITION; COMBUSTION SYNTHESIS; REFRACTORY NITRIDES; TIN COATINGS; NITROGEN; DIFFUSION; PRESSURE; TIO2;

D O I：

10.1016/j.jallcom.2008.09.048

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nanocrystalline titanium nitride has been prepared via a convenient route by the reaction of metallic magnesium powder with titanium dioxide and ammonium chloride in an autoclave at 650 degrees C. X-ray powder diffraction pattern indicated that the product was cubic titanium nitride, and the cell constant was a = 4.261 angstrom. Transmission electron microscopy (TEM) image showed that it consisted of particles with an average size of about 30 nm in diameter. The product was also studied by BET and TGA. It had good thermal stability and oxidation resistance below 350 degrees C in air. (C) 2008 Elsevier B.V. Ail rights reserved.

引用

页码：603 / 605

页数：3

共 28 条

[1] REACTION OF NITROGEN WITH STIRRED AND UNSTIRRED LIQUID LITHIUM [J].

ADDISON, CC ;

DAVIES, BM .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (12) :1822-&

[2] Physical-mechanical properties of nanostructured titanium nitride [J].

Andrievski, RA .

NANOSTRUCTURED MATERIALS, 1997, 9 (1-8) :607-610

[3] TIN COATINGS ON STEEL [J].

BUHL, R ;

PULKER, HK ;

MOLL, E .

THIN SOLID FILMS, 1981, 80 (1-3) :265-270

[4]

ELESKANDARANY MS, 1992, J MATER RES, V7, P888, DOI 10.1557/JMR.1992.0888

[5] EFFECT OF NITROGEN PRESSURE AND DILUENT CONTENT ON THE COMBUSTION SYNTHESIS OF TITANIUM NITRIDE [J].

ESLAMLOOGRAMI, M ;

MUNIR, ZA .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1990, 73 (08) :2222-2227

[6] RAPID SOLID-STATE SYNTHESIS OF REFRACTORY NITRIDES [J].

GILLAN, EG ;

KANER, RB .

INORGANIC CHEMISTRY, 1994, 33 (25) :5693-5700

[7] ALUMINUM DIFFUSION IN TITANIUM NITRIDE FILMS - EFFICIENCY OF TIN BARRIER LAYERS [J].

GRIGOROV, GI ;

GRIGOROV, KG ;

STOYANOVA, M ;

VIGNES, JL ;

LANGERON, JP ;

DENJEAN, P .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1993, 57 (02) :195-197

[8]

Hu JQ, 2000, J AM CERAM SOC, V83, P430

[9] NITRIDATION OF TIO2 FIBERS PREPARED BY THE SOL-GEL METHOD [J].

KAMIYA, K ;

YOKO, T ;

BESSHO, M .

JOURNAL OF MATERIALS SCIENCE, 1987, 22 (03) :937-941

[10] CRYSTAL-GROWTH OF TITANIUM NITRIDE BY CHEMICAL VAPOR-DEPOSITION [J].

KATO, A ;

TAMARI, N .

JOURNAL OF CRYSTAL GROWTH, 1975, 29 (01) :55-60

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