Hexaazatrinaphthylenes with Different Twists

被引:29
作者
Choudhary, Sunil [3 ,4 ]
Gozalvez, Cristian [1 ]
Higelin, Alexander [5 ]
Krossing, Ingo [3 ,5 ]
Melle-Franco, Manuel [6 ]
Mateo-Alonso, Aurelio [1 ,2 ]
机构
[1] Univ Basque Country UPV EHU, POLYMAT, Donostia San Sebastian 20018, Spain
[2] Basque Fdn Sci, Bilbao 48011, Spain
[3] Univ Freiburg, Freiburg Inst Adv Studies FRIAS, Sch Soft Matter Res, D-79104 Freiburg, Germany
[4] Univ Freiburg, Inst Organ Chem & Biochem, D-79104 Freiburg, Germany
[5] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany
[6] Univ Minho, CCTC, P-4710057 Braga, Portugal
关键词
electrochemistry; fluorescence; hexaazatrinaphthylenes; polycyclic aromatic hydrocarbons; twisted aromatics; POLYCYCLIC AROMATIC-HYDROCARBONS; CHARGE-CARRIER MOBILITY; CLEAN REACTION STRATEGY; HEXABENZOTRIPHENYLENE; TRANSISTORS; TWISTACENE; DESIGN; NANOGRAPHENE; DERIVATIVES; PENTACENE;
D O I
10.1002/chem.201304071
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A synthetic strategy that allows the induction of twist angles of different sizes in 5,6,11,12,17,18-hexaazatrinaphthylene (HATNA) chromophores is reported. The different twist angles are accompanied by measurable changes in the emission and electrochemical characteristics of HATNA.
引用
收藏
页码:1525 / 1528
页数:4
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