Ultrahigh Rate Capabilities of Lithium-Ion Batteries from 3D Ordered Hierarchically Porous Electrodes with Entrapped Active Nanoparticles Configuration

被引：152

作者：

Huang, Xin ^{[1
]}

Yu, Hong ^{[1
,2
]}

Chen, Jing ^{[1
,2
]}

Lu, Ziyang ^{[1
]}

Yazami, Rachid ^{[2
]}

Hng, Huey Hoon ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

[2] Nanyang Technol Univ, Energy Res Inst, Singapore 639798, Singapore

来源：

ADVANCED MATERIALS | 2014年 / 26卷 / 08期

基金：

新加坡国家研究基金会;

关键词：

lithium-ion batteries; ultrahigh rate capabilities; hierarchically porous electrodes; transition metal oxides; entrapped-active nanoparticles; ADVANCED ENERGY-CONVERSION; ANODE MATERIALS; HIGH-CAPACITY; COMPOSITE; POLYMERIZATION; NANOMATERIALS; CHALLENGES; FRAMEWORKS; NANOSHEETS; FILMS;

D O I：

10.1002/adma.201304467

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three dimensional (3D) ordered hierarchically porous electrodes with an entrapped active nanoparticles configuration afford an extremely effective conductive 3D network from the micrometer to the nano meter scale for fast electron and Li-ion transport, and also allow the development of a stable solid electrolyte interphase over the electrode materials, therefore exhibiting extraordinary rate capabilities. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1296 / 1303

页数：8

共 38 条

[1] Anisotropy of electronic and ionic transport in LiFePO4 single crystals [J].

Amin, Ruhul ;

Balaya, Palani ;

Maier, Joachim .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2007, 10 (01) :A13-A16

[2] Nanostructured materials for advanced energy conversion and storage devices [J].

Aricò, AS ;

Bruce, P ;

Scrosati, B ;

Tarascon, JM ;

Van Schalkwijk, W .

NATURE MATERIALS, 2005, 4 (05) :366-377

[3] Building better batteries [J].

Armand, M. ;

Tarascon, J. -M. .

NATURE, 2008, 451 (7179) :652-657

[4] XPS AND UV-VIS STUDY OF HIGH-PURITY FE2O3 THIN-FILMS OBTAINED USING THE SOL-GEL TECHNIQUE [J].

ARMELAO, L ;

BERTONCELLO, R ;

CROCIANI, L ;

DEPAOLI, G ;

GRANOZZI, G ;

TONDELLO, E ;

BETTINELLI, M .

JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (01) :79-83

[5] Nanomaterials for rechargeable lithium batteries [J].

Bruce, Peter G. ;

Scrosati, Bruno ;

Tarascon, Jean-Marie .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) :2930-2946

[6] Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions [J].

Cabana, Jordi ;

Monconduit, Laure ;

Larcher, Dominique ;

Rosa Palacin, M. .

ADVANCED MATERIALS, 2010, 22 (35) :E170-E192

[7] Carbon Nanomaterials for Advanced Energy Conversion and Storage [J].

Dai, Liming ;

Chang, Dong Wook ;

Baek, Jong-Beom ;

Lu, Wen .

SMALL, 2012, 8 (08) :1130-1166

[8] Graphene-Based Electrodes [J].

Huang, Xiao ;

Zeng, Zhiyuan ;

Fan, Zhanxi ;

Liu, Juqing ;

Zhang, Hua .

ADVANCED MATERIALS, 2012, 24 (45) :5979-6004

[9] Carbon buffered-transition metal oxide nanoparticle-graphene hybrid nanosheets as high-performance anode materials for lithium ion batteries [J].

Huang, Xin ;

Chen, Jing ;

Yu, Hong ;

Cai, Ren ;

Peng, Shengjie ;

Yan, Qingyu ;

Hng, Huey Hoon .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (23) :6901-6907

[10] Assembly of Tin Oxide/Graphene Nanosheets into 3D Hierarchical Frameworks for High-Performance Lithium Storage [J].

Huang, Yanshan ;

Wu, Dongqing ;

Han, Sheng ;

Li, Shuang ;

Xiao, Li ;

Zhang, Fan ;

Feng, Xinliang .

CHEMSUSCHEM, 2013, 6 (08) :1510-1515

← 1 2 3 4 →