Beyond Traditional Cross Couplings: The Scope of the Cross Dehydrogenative Coupling Reaction

被引：646
作者：
Scheuermann, Caroline J. [1 ]
机构：
[1] Inst Organ Chem, D-70569 Stuttgart, Germany
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2010年 / 5卷 / 03期
关键词：
C-H activation; cross coupling; homogeneous catalysis; oxidation; sustainable catalysis; C-H BONDS; RUTHENIUM-CATALYZED OXIDATION; TERTIARY-AMINES; ACTIVATED METHYLENE; DIRECT ALKYLATION; MOLECULAR-OXYGEN; BENZYL ETHERS; ADJACENT; FUNCTIONALIZATION; AMIDATION;
D O I：
10.1002/asia.200900487
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The development of new and environmentally compatible methods for the synthesis of C-C and C-heteroatom bonds is of great significance to researchers. The cross dehydrogenative coupling (CDC) is emerging as an important tool for chemists with a variety of, often inexpensive, metal catalysts able to perform these reactions both regio- and enantioselectively. Perhaps more importantly CDC methodology has been shown to be extremely environmentally friendly and facile being able to be carried out in aqueous environments under an atmosphere of air. This Focus Review intends to give an overview of the most contemporary developments in this exciting and emerging area of cross-coupling chemistry.
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页码：436 / 451
页数：16
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