Reduction of Surface Friction of Natural Rubber Film Coated with PMMA Particle: Effect of Particle Size

被引:12
作者
Anancharungsuk, Waranya [1 ]
Taweepreda, Wirach [2 ]
Wirasate, Supa [1 ]
Thonggoom, Rattaporn [1 ]
Tangboriboonrat, Pramuan [1 ]
机构
[1] Mahidol Univ, Fac Sci, Dept Chem, Bangkok 10400, Thailand
[2] Prince Songkla Univ, Fac Sci, Polymer Sci Program, Hat Yai 90112, Songkla, Thailand
关键词
emulsion polymerization; films; rubber; self-assembly; surfaces; COLLOIDAL PARTICLES; OPTICAL-PROPERTIES; LATEX FILM; NANOPARTICLES; POLYDISPERSITY; MULTILAYERS; MONOLAYERS; ADSORPTION;
D O I
10.1002/app.31459
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The friction coefficient of the sulphur-prevulcanized natural rubber (SPNR) film could be effectively reduced by deposition of poly(methyl methacrylate) (PMMA) particles. The nanoscale surface roughness of rubber, determined by atomic force microscope, was directly proportional to the particle size of PMMA particle at 12% surface coverage (Cs). The %Cs and surface roughness of the modified SPNR increased, while the friction coefficient decreased, with increasing PMMA latex concentration and immersion time. By using a mixture of latexes having both large and small sizes, the increase in the amount of small particles resulted in the better distribution of large particles deposited on the rubber surface. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 115:3680-3686, 2010
引用
收藏
页码:3680 / 3686
页数:7
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