Formation and X-ray crystal structure determination of the novel triplatinum cluster [(Ph3P)Pt(μ-SiC12H8)]3 from reaction of silafluorene with (Ph3P)2Pt(η2-C2H4)

被引：41

作者：

Braddock-Wilking, J ^{[1
]}

Corey, JY ^{[1
]}

Dill, K ^{[1
]}

Rath, NP ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem & Biochem, St Louis, MO 63121 USA

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 25期

关键词：

D O I：

10.1021/om020565z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of silafluorene (H2SiC12H8) with (Ph3P)(2)Pt(eta(2)-C2H4) in C6D6 (or C7D8) provided the trinuclear complex [(Ph3P)Pt(mu-SiC12H8)](3) (3). The structure of 3, which exhibits a nonplanar Pt3Si3 core, was confirmed by X-ray crystallography.

引用

页码：5467 / 5469

页数：3

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