Kinetics and mechanism of liquid-phase catalytic ozonation of nitrotolueues

被引：2

作者：

Galstyan, A. G. ^{[1
]}

机构：

[1] E Ukrainian Natl Univ, Rubezhnoe Branch, Rubezhnoye, Ukraine

来源：

PETROLEUM CHEMISTRY | 2006年 / 46卷 / 05期

关键词：

D O I：

10.1134/S0965544106050100

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The kinetics of catalytic oxidation of nitrotoluenes with ozone was studied. It was shown that the introduction of transition metal salts into the system makes it possible to prevent almost completely the ozonolysis of the aromatic ring and to direct the process towards methyl-group oxidation yielding benzoic acids. A mechanism of the process that explains the experimental findings was proposed.

引用

页码：362 / 366

页数：5

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