Supramolecular isomerism in coordination polymers

被引：579
作者：
Zhang, Jie-Peng [1 ]
Huang, Xiao-Chun [2 ]
Chen, Xiao-Ming [1 ]
机构：
[1] Sun Yat Sen Univ, MOE Key Lab Bioinorgan & Synthet Chem, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China
[2] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China
来源：
CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 08期
关键词：
METAL-ORGANIC FRAMEWORKS; ZEOLITIC IMIDAZOLATE FRAMEWORKS; SINGLE-CRYSTAL TRANSFORMATIONS; POLYMORPHS; STRUCTURAL TRANSFORMATIONS; CATENATION ISOMERISM; LINEAR SPACER; CENTER-DOT; SOLVENT; COPPER(I);
D O I：
10.1039/b900317g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Coordination polymers have been emerging as a topical research field in crystal engineering, solid-state chemistry, and materials science. Considering the wide occurrence of structural and compositional diversity during self-assembly and crystallization, supramolecular isomerism represents an indication of composition control and structure prediction. Actually, supramolecular isomerism is not just an obstacle or challenge, but also a good opportunity for developing novel materials and a better understanding of self-assembly and crystal growth. This critical review provides an overview of the developing knowledge, in the context of supramolecular isomerism, of the design, synthesis, and properties of coordination polymers (97 references).
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收藏
页码：2385 / 2396
页数：12
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