Mixed Al and Si doping in ferroelectric HfO2 thin films

被引:41
作者
Lomenzo, Patrick D. [1 ]
Takmeel, Qanit [2 ]
Zhou, Chuanzhen [3 ]
Chung, Ching-Chang [4 ]
Moghaddam, Saeed [5 ]
Jones, Jacob L. [4 ]
Nishida, Toshikazu [1 ]
机构
[1] Univ Florida, Dept Elect & Comp Engn, Gainesville, FL 32611 USA
[2] Univ Florida, Dept Mat Sci & Engn, Gainesville, FL 32611 USA
[3] N Carolina State Univ, Coll Engn, Analyt Instrumentat Ctr, Raleigh, NC 27696 USA
[4] N Carolina State Univ, Dept Mat Sci & Engn, Raleigh, NC 27696 USA
[5] Univ Florida, Dept Mech & Aerosp Engn, Gainesville, FL 32611 USA
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.4937588
中图分类号
O59 [应用物理学];
学科分类号
摘要
Ferroelectric HfO2 thin films 10nm thick are simultaneously doped with Al and Si. The arrangement of the Al and Si dopant layers within the HfO2 greatly influences the resulting ferroelectric properties of the polycrystalline thin films. Optimizing the order of the Si and Al dopant layers led to a remanent polarization of similar to 20 mu C/cm(2) and a coercive field strength of similar to 1.2MV/cm. Post-metallization anneal temperatures from 700 degrees C to 900 degrees C were used to crystallize the Al and Si doped HfO2 thin films. Grazing incidence x-ray diffraction detected differences in peak broadening between the mixed Al and Si doped HfO2 thin films, indicating that strain may influence the formation of the ferroelectric phase with variations in the dopant layering. Endurance characteristics show that the mixed Al and Si doped HfO2 thin films exhibit a remanent polarization greater than 15 mu C/cm(2) up to 10(8) cycles. (C) 2015 AIP Publishing LLC.
引用
收藏
页数:5
相关论文
共 19 条
  • [1] Ferroelectricity in hafnium oxide thin films
    Boescke, T. S.
    Mueller, J.
    Braeuhaus, D.
    Schroeder, U.
    Boettger, U.
    [J]. APPLIED PHYSICS LETTERS, 2011, 99 (10)
  • [2] Identification of the ferroelectric switching process and dopant-dependent switching properties in orthorhombic HfO2: A first principles insight
    Clima, S.
    Wouters, D. J.
    Adelmann, C.
    Schenk, T.
    Schroeder, U.
    Jurczak, M.
    Pourtois, G.
    [J]. APPLIED PHYSICS LETTERS, 2014, 104 (09)
  • [3] Pathways towards ferroelectricity in hafnia
    Huan, Tran Doan
    Sharma, Vinit
    Rossetti, George A., Jr.
    Ramprasad, Rampi
    [J]. PHYSICAL REVIEW B, 2014, 90 (06)
  • [4] TaN interface properties and electric field cycling effects on ferroelectric Si-doped HfO2 thin films
    Lomenzo, Patrick D.
    Takmeel, Qanit
    Zhou, Chuanzhen
    Fancher, Chris M.
    Lambers, Eric
    Rudawski, Nicholas G.
    Jones, Jacob L.
    Moghaddam, Saeed
    Nishida, Toshikazu
    [J]. JOURNAL OF APPLIED PHYSICS, 2015, 117 (13)
  • [5] The effects of layering in ferroelectric Si-doped HfO2 thin films
    Lomenzo, Patrick D.
    Takmeel, Qanit
    Zhou, Chuanzhen
    Liu, Yang
    Fancher, Chris M.
    Jones, Jacob L.
    Moghaddam, Saeed
    Nishida, Toshikazu
    [J]. APPLIED PHYSICS LETTERS, 2014, 105 (07)
  • [6] Ferroelectric phenomena in Si-doped HfO2 thin films with TiN and Ir electrodes
    Lomenzo, Patrick D.
    Zhao, Peng
    Takmeel, Qanit
    Moghaddam, Saeed
    Nishida, Toshikazu
    Nelson, Matthew
    Fancher, Chris M.
    Grimley, Everett D.
    Sang, Xiahan
    LeBeau, James M.
    Jones, Jacob L.
    [J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2014, 32 (03):
  • [7] Why is nonvolatile ferroelectric memory field-effect transistor still elusive?
    Ma, TP
    Han, JP
    [J]. IEEE ELECTRON DEVICE LETTERS, 2002, 23 (07) : 386 - 388
  • [8] Ferroelectricity in yttrium-doped hafnium oxide
    Mueller, J.
    Schroeder, U.
    Boescke, T. S.
    Mueller, I.
    Boettger, U.
    Wilde, L.
    Sundqvist, J.
    Lemberger, M.
    Kuecher, P.
    Mikolajick, T.
    Frey, L.
    [J]. JOURNAL OF APPLIED PHYSICS, 2011, 110 (11)
  • [9] Ferroelectric Zr0.5Hf0.5O2 thin films for nonvolatile memory applications
    Mueller, J.
    Boescke, T. S.
    Braeuhaus, D.
    Schroeder, U.
    Boettger, U.
    Sundqvist, J.
    Kuecher, P.
    Mikolajick, T.
    Frey, L.
    [J]. APPLIED PHYSICS LETTERS, 2011, 99 (11)
  • [10] Ferroelectricity in Gd-Doped HfO2 Thin Films
    Mueller, S.
    Adelmann, C.
    Singh, A.
    Van Elshocht, S.
    Schroeder, U.
    Mikolajick, T.
    [J]. ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, 2012, 1 (06) : N123 - N126