Determination of the effective diffusion length of silicon solar cells from photoluminescence

被引:36
作者
Hinken, David [1 ]
Bothe, Karsten [1 ]
Ramspeck, Klaus [1 ]
Herlufsen, Sandra [1 ]
Brendel, Rolf [1 ]
机构
[1] ISFH, D-31860 Emmerthal, Germany
关键词
diffusion; photoluminescence; solar cells; RECOMBINATION; RADIATION;
D O I
10.1063/1.3130408
中图分类号
O59 [应用物理学];
学科分类号
摘要
We present a method to determine the effective diffusion length L-eff of silicon solar cells from photoluminescence (PL) measurements carried out under two different operating conditions. Measuring the photoluminescence emission under open circuit condition (PL-oc), where the solar cell is not contacted at all, and short circuit condition (PL-sc), where the solar cell is held at zero voltage, L-eff directly follows from the ratio of the PL-oc and the PL-sc signals. Detailed knowledge about the optical properties of the experimental setup is not necessary since the optical properties cancel out completely. We explain the theoretical background of our method and derive an analytical description for the PL-oc and the PL-sc luminescence emissions. The applicability of our method is demonstrated by the comparison of effective diffusion lengths from PL measurements with values determined from the analysis of internal quantum efficiency measurements.
引用
收藏
页数:6
相关论文
共 24 条
[1]   Injection dependence of spontaneous radiative recombination in crystalline silicon: Experimental verification and theoretical analysis [J].
Altermatt, P. P. ;
Geelhaar, F. ;
Trupke, T. ;
Dai, X. ;
Neisser, A. ;
Daub, E. .
APPLIED PHYSICS LETTERS, 2006, 88 (26)
[2]  
BASORE PA, 1993, IEEE PHOT SPEC CONF, P147, DOI 10.1109/PVSC.1993.347063
[3]  
Bothe K., 2007, P 22 EUR PHOT SOL EN, P1673
[4]  
Bothe K., 2006, P 21 EUR PHOT SOL EN, P597
[5]   Injection and collection diffusion lengths of polycrystalline thin-film solar cells [J].
Brendel, R ;
Rau, U .
SOLID STATE PHENOMENA, 1999, 67-8 :81-86
[6]   PC1D version 5: 32-bit solar cell modeling on personal computers [J].
Clugston, DA ;
Basore, PA .
CONFERENCE RECORD OF THE TWENTY SIXTH IEEE PHOTOVOLTAIC SPECIALISTS CONFERENCE - 1997, 1997, :207-210
[7]   The effect of emitter recombination on the effective lifetime of silicon wafers [J].
Cuevas, A .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1999, 57 (03) :277-290
[8]   THE EFFICIENCY OF PHOTO-LUMINESCENCE OF THIN EPITAXIAL SEMICONDUCTORS [J].
DUGGAN, G ;
SCOTT, GB .
JOURNAL OF APPLIED PHYSICS, 1981, 52 (01) :407-411
[9]   Scanning IQE-measurement for accurate current determination on very large area solar cells [J].
Fischer, B ;
Keil, M ;
Fath, P ;
Bucher, E .
CONFERENCE RECORD OF THE TWENTY-NINTH IEEE PHOTOVOLTAIC SPECIALISTS CONFERENCE 2002, 2002, :454-457
[10]  
Fischer B., 2003, PhD Thesis