The anion-π interaction: naissance and establishment of a peculiar supramolecular bond

被引：77

作者：

Gamez, Patrick ^{[1
,2
]}

机构：

[1] Univ Barcelona, Dept Quim Inorgan, QBI, E-08028 Barcelona, Spain

[2] ICREA, Barcelona 08010, Spain

来源：

INORGANIC CHEMISTRY FRONTIERS | 2014年 / 1卷 / 01期

关键词：

ION-PAIR RECEPTOR; AROMATIC INTERACTIONS; CATION-PI; AB-INITIO; COMPLEXES; RINGS; RECOGNITION; PERSPECTIVE; SOLVENT;

D O I：

10.1039/c3qi00055a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A decade of thorough theoretical and experimental investigations has established the anion-pi interaction as a new and important supramolecular bond. The present review describes the physical nature of this noncovalent interaction, the different (structural) factors that can influence its strength, and three state-of-the-art literature reports illustrating its rational utilization for the development of anion receptors and biological applications.

引用

页码：35 / 43

页数：9

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