The anion-π interaction: naissance and establishment of a peculiar supramolecular bond

被引：72
|
作者：
Gamez, Patrick [1 ,2 ]
机构：
[1] Univ Barcelona, Dept Quim Inorgan, QBI, E-08028 Barcelona, Spain
[2] ICREA, Barcelona 08010, Spain
来源：
INORGANIC CHEMISTRY FRONTIERS | 2014年 / 1卷 / 01期
关键词：
ION-PAIR RECEPTOR; AROMATIC INTERACTIONS; CATION-PI; AB-INITIO; COMPLEXES; RINGS; RECOGNITION; PERSPECTIVE; SOLVENT;
D O I：
10.1039/c3qi00055a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A decade of thorough theoretical and experimental investigations has established the anion-pi interaction as a new and important supramolecular bond. The present review describes the physical nature of this noncovalent interaction, the different (structural) factors that can influence its strength, and three state-of-the-art literature reports illustrating its rational utilization for the development of anion receptors and biological applications.
引用
收藏
页码：35 / 43
页数：9
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