Enhanced Fischer-Tropsch activity on Co/P-Al2O3 catalyst: Effect of phosphorous content

被引：48

作者：

Bae, Jong Wook ^{[1
]}

Kim, Seung-Moon ^{[1
]}

Lee, Yun-Jo ^{[1
]}

Lee, Min-Jae ^{[1
]}

Jun, Ki-Won ^{[1
]}

机构：

[1] Korea Res Inst Chem Technol, Petr Displacement Technol Res Ctr, Taejon 305600, South Korea

来源：

CATALYSIS COMMUNICATIONS | 2009年 / 10卷 / 09期

关键词：

Fischer-Tropsch synthesis; Cobalt; Phosphorous; Alumina; Redispersion; COBALT CATALYSTS; MESOPOROUS SILICAS; ALUMINA; DEACTIVATION; REACTOR;

D O I：

10.1016/j.catcom.2009.02.023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The phosphorous-modified gamma-Al2O3 support is used to prepare cobalt-based Fischer-Tropsch (FT) catalysts (Co/P-Al2O3) by slurry impregnation method. Since alumina surface is partially transformed to aluminum phosphate by phosphorous modification, it alters the cobalt cluster size resulting in the changes of FT activity. The appropriate amount of phosphorous loading on alumina surface is around 1-2 wt.% based on the alumina support. The enhanced activity is mainly attributed to the formation of a homogeneously distributed small cobalt clusters and redispersion of cobalt species during the FT reaction. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1358 / 1362

页数：5

共 23 条

[1] Influence of pH of the impregnation solution on the catalytic properties of Co/γ-alumina for Fischer-Tropsch synthesis [J].

Bae, Jong Wook ;

Lee, Yun-Jo ;

Park, Jo-Yong ;

Jun, Ki-Won .

ENERGY & FUELS, 2008, 22 (05) :2885-2891

[2] Structure, texture, surface acidity, and catalytic activity of AlPO4-ZrO2 (5-50 wt% ZrO2) catalysts prepared by a sol-gel procedure [J].

Bautista, FM ;

Campelo, JM ;

Garcia, A ;

Luna, D ;

Marinas, JM ;

Romero, AA ;

Colon, G ;

Navio, JA ;

Macias, M .

JOURNAL OF CATALYSIS, 1998, 179 (02) :483-494

[3] Cobalt particle size effects in the Fischer-Tropsch reaction studied with carbon nanofiber supported catalysts [J].

Bezemer, GL ;

Bitter, JH ;

Kuipers, HPCE ;

Oosterbeek, H ;

Holewijn, JE ;

Xu, XD ;

Kapteijn, F ;

van Dillen, AJ ;

de Jong, KP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (12) :3956-3964

[4] Fischer-Tropsch synthesis over γ-calumina-supported cobalt catalysts:: Effect of support variables [J].

Borg, Oyvind ;

Erib, Sigrid ;

Blekkan, Edd A. ;

Storsaeter, Solvi ;

Wigum, Hanne ;

Rytter, Erling ;

Holmen, Anders .

JOURNAL OF CATALYSIS, 2007, 248 (01) :89-100

[5] Monolith loop catalytic membrane reactor for Fischer-Tropsch synthesis [J].

Bradford, MCJ ;

Te, M ;

Pollack, A .

APPLIED CATALYSIS A-GENERAL, 2005, 283 (1-2) :39-46

[6] Synthesis, characterization, and catalytic properties of vanadium oxide catalysts supported on AlPO4 [J].

Chary, KVR ;

Kishan, G ;

Ramesh, K ;

Kumar, CP ;

Vidyasagar, G .

LANGMUIR, 2003, 19 (11) :4548-4554

[7] Fischer-Tropsch synthesis: Overview of reactor development and future potentialities [J].

Davis, BH .

TOPICS IN CATALYSIS, 2005, 32 (3-4) :143-168

[8] The Fischer-Tropsch process: 1950-2000 [J].

Dry, ME .

CATALYSIS TODAY, 2002, 71 (3-4) :227-241

[9]

IGLESIA E, 1997, APPL CATAL A-GEN, V161, P9

[10]

IWAMOTO R, 2000, ADV CATAL, V44, P417, DOI DOI 10.1016/50360-0564(08)60516-7

← 1 2 3 →