Direct Synthesis of Phenol from Benzene by Pd - VOx Nanoparticles Using Molecular Oxygen

被引：15

作者：

Shang, Sensen ^{[1
,2
]}

Yang, Hua ^{[1
,2
]}

Li, Jun ^{[1
]}

Chen, Bo ^{[1
,2
]}

Lv, Ying ^{[1
]}

Gao, Shuang ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 10049, Peoples R China

来源：

CHEMPLUSCHEM | 2014年 / 79卷 / 05期

基金：

中国国家自然科学基金;

关键词：

benzene; hydroxylation; nanoparticles; phenol; synthetic methods; ONE-STEP HYDROXYLATION; SOLVENT-FREE OXIDATION; CARBON-HYDROGEN BONDS; CATALYTIC-OXIDATION; NITROUS-OXIDE; ACTIVATION; PEROXIDE; ARYLATION; AROMATICS; ALDEHYDES;

D O I：

10.1002/cplu.201400007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel PdVOx nanoparticles (NPs) prepared by a one-pot hydrogenation method are reported. X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, and UV/Vis spectroscopy were performed to characterize the PdVOx NPs. The NPs catalyzed benzene directly to phenol in 5.2% yield with more than 99% selectivity using O-2 as the sole oxidant.

引用

页码：680 / 683

页数：4

共 40 条

[1]

Ackermann L., 2009, ANGEW CHEM, V121, P9976, DOI DOI 10.1002/ANGE.200902996

[2] Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by C-H Bond Cleavage [J].

Ackermann, Lutz ;

Vicente, Ruben ;

Kapdi, Anant R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (52) :9792-9826

[3]

[Anonymous], 2000, ANGEW CHEM INT ED

[4]

[Anonymous], 2010, ANGEW CHEM

[5] One-Step Hydroxylation of Benzene to Phenol Over Layered Double Hydroxides and their Derived Forms [J].

Antonyraj, Churchil A. ;

Srinivasan, Kannan .

CATALYSIS SURVEYS FROM ASIA, 2013, 17 (02) :47-70

[6] Transition metal-catalyzed arylation of unactivated C(sp3)-H bonds [J].

Baudoin, Olivier .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (10) :4902-4911

[7]

Bianchi D, 2000, ANGEW CHEM INT EDIT, V39, P4321, DOI 10.1002/1521-3773(20001201)39:23<4321::AID-ANIE4321>3.0.CO

[8]

2-5

[9] A Vanadyl Complex Grafted to Periodic Mesoporous Organosilica: A Green Catalyst for Selective Hydroxylation of Benzene to Phenol [J].

Borah, Parijat ;

Ma, Xing ;

Kim Truc Nguyen ;

Zhao, Yanli .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (31) :7756-7761

[10] On the involvement of radical oxygen species O- in catalytic oxidation of benzene to phenol by nitrous oxide [J].

Chernyavsky, Valery S. ;

Pirutko, Larisa V. ;

Uriarte, Anthony K. ;

Kharitonov, Alexander S. ;

Panov, Gennady I. .

JOURNAL OF CATALYSIS, 2007, 245 (02) :466-469

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