Abnormal Inverse Current during Anion Deintercalation from Graphite Electrode

被引：16

作者：

Huang, Yuhao ^{[1
,2
]}

Li, Jiayu ^{[1
,2
]}

Wang, Hongyu ^{[1
,2
,3
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, 96 Jinzhai Rd, Hefei 230026, Anhui, Peoples R China

[2] Univ Sci & Technol China, Sch Appl Chem & Engn, 96 Jinzhai Rd, Hefei 230026, Anhui, Peoples R China

[3] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, 5625 Renmin St, Changchun 130022, Jilin, Peoples R China

来源：

ACS APPLIED ENERGY MATERIALS | 2019年 / 2卷 / 06期

基金：

中国国家自然科学基金;

关键词：

countercurrent; backflow; resolvation; anion intercalation; dual-ion battery; tetrafluoroborate; ethylene carbonate; graphite; X-RAY-DIFFRACTION; ELECTROCHEMICAL INTERCALATION; BIS(TRIFLUOROMETHANESULFONYL)IMIDE ANIONS; POSITIVE ELECTRODE; IMIDE ANIONS; PERFORMANCE; INSIGHTS; BEHAVIOR; VOLTAGE; CARBONS;

D O I：

10.1021/acsaem.9b00792

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It was taken for granted that the charge and discharge processes correspond with distinctly opposite directions of ionic flow when the energy storage mechanism of dual ion battery was concerned. This common sense is challenged as we find a remarkable countercurrent in the cyclic voltammetric curve during the deintercalation of tetrafluoroborate anions from graphite electrode using ethylene carbonate solution. By electrochemical analysis, there is believed to be backflow of anions during the deintercalation process. The cause of this abnormal ionic flow relates to both the desolvation and resolvation of the intercalated anions inside the graphite electrode. Supportive evidence is provided.

引用

页码：4544 / 4550

页数：13

共 50 条

[31] Reversible anion intercalation into graphite from aluminum perchlorate "water-in-salt" electrolyte [J].

Zafar, Zahid Ali ;

Abbas, Ghulam ;

Silhavik, Martin ;

Knizek, Karel ;

Kaman, Ondrej ;

Sonia, Farjana J. ;

Kumar, Prabhat ;

Jiricek, Petr ;

Houdkova, Jana ;

Frank, Otakar ;

Cervenka, Jiri .

ELECTROCHIMICA ACTA, 2022, 404

[32] Anion Intercalation into Graphite Electrode from Ethylene Carbonate Solutions Dissolving both Lithium Hexafluorophosphate and Lithium Bis(trifluoromethanesulfonyl)imide [J].

Liu, Haibo ;

Zhang, Jia ;

Zhang, Lei ;

Xu, Guobao ;

Wang, Hongyu .

JOURNAL OF PHYSICAL CHEMISTRY C, 2024, 128 (04) :1574-1581

[33] CARBON MICROFIBERS GROWN ON GRAPHITE ELECTRODE DURING FULLERENE GENERATION USING COMPOSITE GRAPHITE RODS [J].

ATA, M ;

KIJIMA, Y ;

IMOTO, H ;

MATSUZAWA, N ;

TAKAHASHI, N .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 1994, 33 (7A) :4032-4038

[34] On the PF6- anion intercalation in graphite from sodium salt-based electrolytes containing different mixtures of organic carbonates [J].

Camean, Ignacio ;

Cuesta, Nuria ;

Garcia, Ana B. .

ELECTROCHIMICA ACTA, 2021, 384

[35] Experimental and computational studies of electrochemical anion intercalation into graphite from target-oriented designed borate-based ionic liquid electrolytes [J].

Beltrop, Kolja ;

Madrid, Jose Carlos Madrid ;

Meister, Paul ;

Heckmann, Andreas ;

Winter, Martin ;

Akbay, Taner ;

Ishihara, Tatsumi ;

Placke, Tobias .

JOURNAL OF POWER SOURCES, 2020, 469

[36] STRUCTURES OF CARBON DEPOSITS FORMED ON A GRAPHITE ELECTRODE DURING FULLERENE GENERATION [J].

ATA, M ;

MATSUZAWA, N ;

KIJIMA, Y ;

SETO, JE ;

IMOTO, H .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1993, 32 (08) :3549-3555

[37] Abnormal electrode behavior of graphite anode operating with the electrolyte containing vinylene carbonate and ethylene sulfite additives [J].

Zhou, Kai ;

Yang, Haohua ;

Zhou, Jianhua ;

Tian, Yan ;

Guo, Jingwen ;

Yuan, Meihui ;

Liu, Libin ;

Gai, Ligang .

ELECTROCHIMICA ACTA, 2023, 462

[38] Electrochemical Introduction/Extraction of Fluoride Ions into/from Graphene-like Graphite for Positive Electrode Materials of Fluoride-Ion Shuttle Batteries [J].

Inoo, Akane ;

Inamoto, Junichi ;

Matsuo, Yoshiaki .

ACS APPLIED MATERIALS & INTERFACES, 2022, 14 (51) :56678-56684

[39] Operando structural analysis of phase transition of graphite electrode during Li de-intercalation process using neutron and synchrotron radiation X-ray diffraction [J].

Takagi, Shigeharu ;

Shimoda, Keiji ;

Haruyama, Jun ;

Kiuchi, Hisao ;

Okazaki, Ken-ichi ;

Fukunaga, Toshiharu ;

Ogumi, Zempachi ;

Abe, Takeshi .

CARBON, 2023, 215

[40] Transition of current of lithium intercalation from solution to graphite [J].

Wang, Xiaoxia ;

Aoki, Koichi .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2007, 604 (02) :101-108

← 1 2 3 4 5 →